Destabilisation of a carbocation by α-oxygen substitution: the hydrolysis of orthocarbonates
作者： Pramod Kandanarachchi , Michael L. Sinnott
DOI: 10.1039/C39920000777
关键词:
摘要: Tetraphenyl orthocarbonate is hydrolysed by general acids 101-fold slower than triphenyl orthoformate, whilst tetrakis(p-methoxyphenyl) faster tetraphenyl orthocarbonate, with a Bronsted α-value closer to orthoformate indicating that cation stability, not an early transition state, the cause of lower rate orthocarbonate.
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