Enantiodivergent Synthesis of Both Enantiomeric Forms of Substituted Paraconic Acids Starting from D-Mannitol as a Chiral Pool.
作者： Yukio Masaki , Hideki Arasaki , Akichika Itoh
DOI: 10.1016/S0040-4039(99)00855-2
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摘要: Abstract Acetamide-acetal Claisen rearrangement of the C 2 -symmetric enediol easily derived from d -mannitol provided a chiral C8-building block, which was demonstrated to be versatile for divergent synthesis both enantiomeric forms substituted paraconic acids.
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