Electrochemical Properties of LiNi 0.8 Co 0.16 Al 0.04 O 2 and Surface Modification with Co 3 (PO 4 ) 2 as Cathode Materials for Lithium Battery

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DOI: 10.5012/BKCS.2008.29.9.1737

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摘要: The electrochemical and thermal stability of were studied before after coating. Different to conventional coating material such as or AlPO4, the layer was not detected clearly by TEM analysis, indicating that nanoparticles effectively reacted with surface impurities . coated sample showed similar capacity at a low C rate condition. However, capability significantly improved effect. It is associated decrease impedance because can act major barrier for overall cell performances in high cycling. In DSC profile charged sample, exothermic peaks shifted temperatures heat generation reduced coating, reaction between electrode electrolyte sucessfully suppressed nanoparticle

参考文章(29)
Ilias Belharouak, Wenquan Lu, Donald Vissers, Khalil Amine, Safety characteristics of Li(Ni0.8Co0.15Al0.05)O2 and Li(Ni1/3Co1/3Mn1/3)O2 Electrochemistry Communications. ,vol. 8, pp. 329- 335 ,(2006) , 10.1016/J.ELECOM.2005.12.007
Yasunori Nishida, Kenji Nakane, Tomoari Satoh, Synthesis and properties of gallium-doped LiNiO2 as the cathode material for lithium secondary batteries Journal of Power Sources. ,vol. 68, pp. 561- 564 ,(1997) , 10.1016/S0378-7753(97)02535-4
Jaephil Cho, Yong Jeong Kim, Tae-Joon Kim, Byungwoo Park, Zero-Strain Intercalation Cathode for Rechargeable Li-Ion Cell Angewandte Chemie International Edition. ,vol. 40, pp. 3367- 3369 ,(2001) , 10.1002/1521-3773(20010917)40:18<3367::AID-ANIE3367>3.0.CO;2-A
A. M. Andersson, D. P. Abraham, R. Haasch, S. MacLaren, J. Liu, K. Amine, Surface Characterization of Electrodes from High Power Lithium-Ion Batteries Journal of The Electrochemical Society. ,vol. 149, ,(2002) , 10.1149/1.1505636
Kazutoshi Matsumoto, Ryuichi Kuzuo, Kaname Takeya, Atsushi Yamanaka, Effects of CO2 in air on Li deintercalation from LiNi1−x−yCoxAlyO2 Journal of Power Sources. ,vol. 81, pp. 558- 561 ,(1999) , 10.1016/S0378-7753(99)00216-5
J. Vetter, P. Novák, M.R. Wagner, C. Veit, K.-C. Möller, J.O. Besenhard, M. Winter, M. Wohlfahrt-Mehrens, C. Vogler, A. Hammouche, Ageing mechanisms in lithium-ion batteries Journal of Power Sources. ,vol. 147, pp. 269- 281 ,(2005) , 10.1016/J.JPOWSOUR.2005.01.006
Jaephil Cho, Yong Jeong Kim, Byungwoo Park, LiCoO2 Cathode Material That Does Not Show a Phase Transition from Hexagonal to Monoclinic Phase Journal of The Electrochemical Society. ,vol. 148, ,(2001) , 10.1149/1.1397772
Jaephil Cho, Joon-Gon Lee, Byoungsoo Kim, Tae-Gon Kim, Jisuk Kim, Byungwoo Park, Control of AlPO4-nanoparticle coating on LiCoO2 by using water or ethanol Electrochimica Acta. ,vol. 50, pp. 4182- 4187 ,(2005) , 10.1016/J.ELECTACTA.2005.01.039
Jaephil Cho, Hyemin Kim, Byungwoo Park, Comparison of Overcharge Behavior of AlPO4-Coated LiCoO2 and LiNi0.8Co0.1Mn0.1 O 2 Cathode Materials in Li-Ion Cells Journal of The Electrochemical Society. ,vol. 151, ,(2004) , 10.1149/1.1790511
H. S. Liu, Z. R. Zhang, Z. L. Gong, Y. Yang, Origin of deterioration for LiNiO2 cathode material during storage in air Electrochemical and Solid State Letters. ,vol. 7, ,(2004) , 10.1149/1.1738471