Chemical Transformations of Tetracyclo[3.3.1.1.3,7.0.1,3]decane (1,3-Dehydroadamantane): VIII. Reaction of 1,3-Dehydroadamantane with Aliphatic Aldehydes
作者： V. M. Mokhov , K. R. Saad , G. Yu. Parshin , G. M. Butov
DOI: 10.1134/S1070428019050099
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摘要: The reaction of 1,3-dehydroadamantane with aliphatic aldehydes involves the Ca-H bond and forms hardly accessible branched 2-(1-adamantyl)alkylaldehydes in one stage a yield 60-78%. It is found that are prone to oligomerization. 2-(1-adamantyl)-alkylaldehydes 2,4-dinitrophenylhydrazine gave corresponding hydrazones 84-98%.
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