Schwingungsspektren und Kraftkonstanten des Methylxanthogenations-d0 und -d3

作者: R. Mattes , G. Pauleickhoff

DOI: 10.1016/0584-8539(73)80197-7

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摘要: Abstract The i.r. and Raman spectra of potassium methyl xanthate- d 0 - 3 are reported. A '-fundamentals assigned on the basis a normal coordinate analysis with 21 parameter generalized valence force field. constants CO OC bonds 4.85 4.90 mdyn respectively. This shows that canonical form CH O + = CS 2 2− makes an insignificant contribution to structure xanthate ion.

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