Effects of anode flooding on the performance degradation of polymer electrolyte membrane fuel cells

作者: Mansu Kim , Namgee Jung , KwangSup Eom , Sung Jong Yoo , Jin Young Kim

DOI: 10.1016/J.JPOWSOUR.2014.04.092

关键词:

摘要: Abstract Polymer electrolyte membrane fuel cell (PEMFC) stacks in a vehicle can be inevitably exposed to harsh environments such as cold weather winter, causing water flooding by the direct flow of condensed electrodes. In this study, anode was experimentally investigated with generated cooling gas line during long-term operation (∼1600 h). The results showed that performance PEMFC considerably degraded. After experiment, thickness decreased, and ratio Pt carbon increased. Moreover, repeated starvation half-cell severely oxidized surface due high induced potential (>1.5 VRHE). cyclic voltammogram experiments indicated characteristic feature similar single under conditions experiment. Therefore, caused severe corrosion because electrode locally increased >1.0 VRHE. Consequently, density tri-phase boundary decreased carbons supporting nanoparticles anode.

参考文章(35)
Gu-Gon Park, Young-Jun Sohn, Tae-Hyun Yang, Young-Gi Yoon, Won-Yong Lee, Chang-Soo Kim, Effect of PTFE contents in the gas diffusion media on the performance of PEMFC Journal of Power Sources. ,vol. 131, pp. 182- 187 ,(2004) , 10.1016/J.JPOWSOUR.2003.12.037
Rak-Hyun Song, Chang-Soo Kim, Dong Ryul Shin, Effects of flow rate and starvation of reactant gases on the performance of phosphoric acid fuel cells Journal of Power Sources. ,vol. 86, pp. 289- 293 ,(2000) , 10.1016/S0378-7753(99)00450-4
Akira Taniguchi, Tomoki Akita, Kazuaki Yasuda, Yoshinori Miyazaki, Analysis of electrocatalyst degradation in PEMFC caused by cell reversal during fuel starvation Journal of Power Sources. ,vol. 130, pp. 42- 49 ,(2004) , 10.1016/J.JPOWSOUR.2003.12.035
Dong Liang, Qiang Shen, Ming Hou, Zhigang Shao, Baolian Yi, Study of the cell reversal process of large area proton exchange membrane fuel cells under fuel starvation Journal of Power Sources. ,vol. 194, pp. 847- 853 ,(2009) , 10.1016/J.JPOWSOUR.2009.06.059
N. Yousfi-Steiner, Ph. Moçotéguy, D. Candusso, D. Hissel, A. Hernandez, A. Aslanides, A review on PEM voltage degradation associated with water management: Impacts, influent factors and characterization Journal of Power Sources. ,vol. 183, pp. 260- 274 ,(2008) , 10.1016/J.JPOWSOUR.2008.04.037
Jan Hendrik Ohs, Ulrich Sauter, Sebastian Maass, Detlef Stolten, Modeling hydrogen starvation conditions in proton-exchange membrane fuel cells Journal of Power Sources. ,vol. 196, pp. 255- 263 ,(2011) , 10.1016/J.JPOWSOUR.2010.06.038
Renato A Antunes, Mara Cristina L Oliveira, Gerhard Ett, Volkmar Ett, None, Corrosion of metal bipolar plates for PEM fuel cells: A review International Journal of Hydrogen Energy. ,vol. 35, pp. 3632- 3647 ,(2010) , 10.1016/J.IJHYDENE.2010.01.059
Masanori Hara, Junji Inukai, Byungchan Bae, Takayuki Hoshi, Kenji Miyatake, Makoto Uchida, Hiroyuki Uchida, Masahiro Watanabe, Micro-Raman study on water distribution inside a Nafion membrane during operation of polymer electrolyte fuel cell Electrochimica Acta. ,vol. 82, pp. 277- 283 ,(2012) , 10.1016/J.ELECTACTA.2012.04.099
A Pozio, M De Francesco, A Cemmi, F Cardellini, L Giorgi, Comparison of high surface Pt/C catalysts by cyclic voltammetry Journal of Power Sources. ,vol. 105, pp. 13- 19 ,(2002) , 10.1016/S0378-7753(01)00921-1
Anders Lundblad, Pehr Björnbom, The Effect of Starvation on Wetting and Electrolyte Distribution in Hydrophobic Gas Diffusion Electrodes Journal of The Electrochemical Society. ,vol. 139, pp. 1337- 1342 ,(1992) , 10.1149/1.2069408