Evaluation of humic-pesticide interactions on the acute toxicity of selected organophosphate and carbamate insecticides.

作者: William H. Benson , Scott F. Long

DOI: 10.1016/0147-6513(91)90069-2

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摘要: The ability of water resource managers to accurately predict the toxicity agricultural chemicals in aquatic ecosystems is essential for development reliable quality standards. At present, accurate predictions are difficult due paucity data concerning interaction these with organic constituents freshwater chemical matrix. Dissolved humic materials ubiquitous components and can affect availability environment. In present investigation, influence acid (HA) on acute selected organophosphate carbamate insecticides was examined using a bacterial bioluminescence inhibition assay. EC50 values pesticides were determined presence 0, 0.5, 5.0, 50, 100 mg/liter HA. A combination antagonistic synergistic effects observed examined. HA significantly reduced azinophos-methyl, chlorpyrifos, carbofuran, while enhanced methyl parathion carbaryl. These results indicate that humic-pesticide interactions alter chemicals. Moreover, dependent temporal relationships concentration.

参考文章(31)
C Curtis, A Lima, SJ Lozano, GD Veith, Evaluation of a Bacterial Bioluminescence Bioassay as a Method for Predicting Acute Toxicity of Organic Chemicals to Fish ASTM special technical publications. pp. 170- 178 ,(1982) , 10.1520/STP36717S
AA Bulich, MW Greene, DL Isenberg, Reliability of the Bacterial Luminescence Assay for Determination of the Toxicity of Pure Compounds and Complex Effluents ASTM special technical publications. pp. 338- 347 ,(1981) , 10.1520/STP34166S
AA Qureshi, KW Flood, SR Thompson, SM Janhurst, CS Inniss, DA Rokosh, Comparison of a Luminescent Bacterial Test with Other Bioassays for Determining Toxicity of Pure Compounds and Complex Effluents ASTM special technical publications. pp. 179- 195 ,(1982) , 10.1520/STP36718S
ME Lebsack, AD Anderson, GM DeGraeve, HL Bergman, Comparison of Bacterial Luminescence and Fish Bioassay Results for Fossil-Fuel Process Waters and Phenolic Constituents ASTM special technical publications. pp. 348- 356 ,(1981) , 10.1520/STP34167S
G. J. Leversee, P. F. Landrum, J. P. Giesy, T. Fannin, Humic Acids Reduce Bioaccumulation of Some Polycyclic Aromatic Hydrocarbons Canadian Journal of Fisheries and Aquatic Sciences. ,vol. 40, pp. s63- s69 ,(1983) , 10.1139/F83-311
G. E. Carlberg, K. Martinsen, A. Kringstad, E. Gjessing, M. Grande, T. K�llqvist, J. U. Sk�re, Influence of aquatic humus on the bioavailability of chlorinated micropollutants in Atlantic salmon. Archives of Environmental Contamination and Toxicology. ,vol. 15, pp. 543- 548 ,(1986) , 10.1007/BF01056568
Paul D Boehm, James G Quinn, Solubilization of hydrocarbons by the dissolved organic matter in sea water Geochimica et Cosmochimica Acta. ,vol. 37, pp. 2459- 2477 ,(1973) , 10.1016/0016-7037(73)90292-5
Cary T. Chiou, Daniel E. Kile, Terry I. Brinton, Ronald L. Malcolm, Jerry A. Leenheer, Patrick. MacCarthy, A comparison of water solubility enhancements of organic solutes by aquatic humic materials and commercial humic acids Environmental Science & Technology. ,vol. 21, pp. 1231- 1234 ,(1987) , 10.1021/ES00165A012
Gary L. Phipps, Gary W. Holcombe, James T. Fiandt, Acute toxicity of phenol and substituted phenols to the fathead minnow. Bulletin of Environmental Contamination and Toxicology. ,vol. 26, pp. 585- 593 ,(1981) , 10.1007/BF01622141