Systems Manifesting Superposed Elastic and Viscous Behavior

作者: A. V. Tobolsky , R. D. Andrews

DOI: 10.1063/1.1723966

关键词:

摘要: Actual substances exhibit a very complicated behavior under mechanical stresses which cannot be described by classical elasticity theory nor the of hydrodynamics viscous fluids. A general molecular describing matter stress is discussed and related to previous investigations experimental observations. Particular attention devoted rubberlike for theories are definitely inadequate. Experimental results on relaxation creep rubbers interpreted in terms modern structural concepts. It found that these three regions stress‐temperature‐time dependence. At intermediate temperatures there exists region relative stability statistical‐thermodynamic rubber valid. elevated caused chemical changes involving rupture formation primary valence bonds. These changes, responsi...

参考文章(6)
M. Mooney, W. E. Wolstenholme, D. S. Villars, Drift and Relaxation of Rubber Journal of Applied Physics. ,vol. 15, pp. 324- 337 ,(1944) , 10.1063/1.1707435
A. V. Tobolsky, I. B. Prettyman, J. H. Dillon, Stress Relaxation of Natural and Synthetic Rubber Stocks Journal of Applied Physics. ,vol. 15, pp. 380- 395 ,(1944) , 10.1063/1.1707442
Hubert M. James, Eugene Guth, Theory of the Elastic Properties of Rubber The Journal of Chemical Physics. ,vol. 11, pp. 455- 481 ,(1943) , 10.1063/1.1723785
Arthur Tobolsky, Henry Eyring, Mechanical Properties of Polymeric Materials The Journal of Chemical Physics. ,vol. 11, pp. 125- 134 ,(1943) , 10.1063/1.1723812
Henry Eyring, Viscosity, Plasticity, and Diffusion as Examples of Absolute Reaction Rates The Journal of Chemical Physics. ,vol. 4, pp. 283- 291 ,(1936) , 10.1063/1.1749836
Frederick T. Wall, Statistical Thermodynamics of Rubber. II The Journal of Chemical Physics. ,vol. 10, pp. 485- 488 ,(1942) , 10.1063/1.1723753