Chirality of Living Systems: A Helping Hand from Crystals and Oligopeptides
作者： Pedro Cintas
DOI: 10.1002/1521-3773(20020402)41:7<1139::AID-ANIE1139>3.0.CO;2-9
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摘要: Left-right asymmetry is ubiquitous in nature. Recent studies reveal changes the energy and growth rate of crystal surfaces to which D or L amino acids bind, with binding itself being dictated by stereochemical matching. Likewise, oligomerization appears be a chiroselective process that enables propagation sequences defined handedness.[[For definition self-assembly, see: M. Bolli, R. Micura, A. Eschenmoser, Chem. Biol. 1997, 4, 309-320.]] These results, along related findings on symmetry breaking further amplification at supramolecular level, constitute new insights into origin homochirality living species.
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