One-step and eco-friendly modification of cellulose membranes by polymer grafting

作者: Julie Credou , Rita Faddoul , Thomas Berthelot

DOI: 10.1039/C4RA11219A

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摘要: The increasing environmental awareness has stimulated the use of bio-based materials and processes. As an affordable sustainable biopolymer, cellulose is ideal engineering material. Beyond paper, finds applications in many areas such as composites, electronics drug delivery. To fulfil these new functions, needs to acquire properties, which commonly done by graft polymerization acrylic compounds. While modification usually performed through complex expensive procedures, diazonium-based polymer grafting procedure presented here was water, at room temperature, a short single step. Cellulose sheets have been successfully grafted with several polymers, first globally dipping then locally inkjet printing. process developed herein simple, eco-friendly mostly time cost-saving. More generally, it powerful tool for easy, robust patterned copolymerization various monomers even monomers.

参考文章(33)
Alexandre Garcia, Nassim Hanifi, Bruno Jousselme, Pascale Jégou, Serge Palacin, Pascal Viel, Thomas Berthelot, Polymer Grafting by Inkjet Printing: A Direct Chemical Writing Toolset Advanced Functional Materials. ,vol. 23, pp. 3668- 3674 ,(2013) , 10.1002/ADFM.201203544
Wassila Dahou, Djamila Ghemati, Atika Oudia, Djamel Aliouche, Preparation and biological characterization of cellulose graft copolymers Biochemical Engineering Journal. ,vol. 48, pp. 187- 194 ,(2010) , 10.1016/J.BEJ.2009.10.006
Robert Pelton, Bioactive paper provides a low-cost platform for diagnostics. Trends in Analytical Chemistry. ,vol. 28, pp. 925- 942 ,(2009) , 10.1016/J.TRAC.2009.05.005
Kuisma Littunen, Ulla Hippi, Leena-Sisko Johansson, Monika Österberg, Tekla Tammelin, Janne Laine, Jukka Seppälä, Free radical graft copolymerization of nanofibrillated cellulose with acrylic monomers Carbohydrate Polymers. ,vol. 84, pp. 1039- 1047 ,(2011) , 10.1016/J.CARBPOL.2010.12.064
Dieter Klemm, Friederike Kramer, Sebastian Moritz, Tom Lindström, Mikael Ankerfors, Derek Gray, Annie Dorris, Nanocelluloses: A New Family of Nature-Based Materials Angewandte Chemie. ,vol. 50, pp. 5438- 5466 ,(2011) , 10.1002/ANIE.201001273
Vincent Mévellec, Sébastien Roussel, Lorraine Tessier, Jérôme Chancolon, Martine Mayne-LʼHermite, Guy Deniau, Pascal Viel, Serge Palacin, None, Grafting Polymers on Surfaces: A New Powerful and Versatile Diazonium Salt-Based One-Step Process in Aqueous Media Chemistry of Materials. ,vol. 19, pp. 6323- 6330 ,(2007) , 10.1021/CM071371I
Andres W. Martinez, Scott T. Phillips, George M. Whitesides, Emanuel Carrilho, Diagnostics for the Developing World: Microfluidic Paper-Based Analytical Devices Analytical Chemistry. ,vol. 82, pp. 3- 10 ,(2010) , 10.1021/AC9013989
Michikazu Hara, Chad C. Waraksa, John T. Lean, Bradley A. Lewis, Thomas E. Mallouk, Photocatalytic Water Oxidation in a Buffered Tris(2,2‘-bipyridyl)ruthenium Complex-Colloidal IrO2 System Journal of Physical Chemistry A. ,vol. 104, pp. 5275- 5280 ,(2000) , 10.1021/JP000321X
Dieter Klemm, Brigitte Heublein, Hans-Peter Fink, Andreas Bohn, Cellulose: Fascinating Biopolymer and Sustainable Raw Material Angewandte Chemie. ,vol. 44, pp. 3358- 3393 ,(2005) , 10.1002/ANIE.200460587
Debashish Roy, Mona Semsarilar, James T. Guthrie, Sébastien Perrier, Cellulose modification by polymer grafting: a review Chemical Society Reviews. ,vol. 38, pp. 2046- 2064 ,(2009) , 10.1039/B808639G