DEVIATIONS FROM BULK MORPHOLOGIES IN THIN FILMS OF BLOCK COPOLYMER/ADDITIVE BINARY BLENDS
作者： Xin-yu Wei , Wei-yin Gu , Xiao-bo Shen , Joseph Strzalka , Zhang Jiang
DOI: 10.1007/S10118-013-1320-X
关键词:
摘要: Deviations from bulk morphologies in thin films of binary blends alkyne-functionalized diblock copolymer poly(ethylene oxide)-block-poly(n-butyl methacrylate-random-propargyl methacrylate) (PEO-b-P(nBMA-r-PgMA)) and Rhodamine B azide are reported, where thermal click reaction between the two components leads to microphase separated morphologies. Both films, increasing loading ratio resulted transition a lamellar microdomain morphology hexagonally packed cylindrical mircodomain morphology. However, lamellae-cylinder was observed at different ratio, which determined by film thickness. As result, significant deviations were observed. These results indicate that surface interactions confined geometry can play an important role dictating BCP/additive blends.
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Alexander Sidorenko, Igor Tokarev, Sergiy Minko, Manfred Stamm, Ordered reactive nanomembranes/nanotemplates from thin films of block copolymer supramolecular assembly. Journal of the American Chemical Society. ,vol. 125, pp. 12211- 12216 ,(2003) , 10.1021/JA036085W
Eunhye Kim, Hyungju Ahn, Du Yeol Ryu, Jehan Kim, Junhan Cho, Transition Behavior of Weakly Interacting PS-b-PMMA Films on Preferential Surfaces: A Direct Observation by GISAXS Macromolecules. ,vol. 42, pp. 8385- 8391 ,(2009) , 10.1021/MA901399V
Cheolmin Park, Jongseung Yoon, Edwin L. Thomas, Enabling nanotechnology with self assembled block copolymer patterns Polymer. ,vol. 44, pp. 6725- 6760 ,(2003) , 10.1016/J.POLYMER.2003.08.011
Changhak Shin, Hyungju Ahn, Eunhye Kim, Du Yeol Ryu, June Huh, Kwang-Woo Kim, Thomas P. Russell, Transition behavior of block copolymer thin films on preferential surfaces Macromolecules. ,vol. 41, pp. 9140- 9145 ,(2008) , 10.1021/MA801778M
E. Huang, P. Mansky, T. P. Russell, C. Harrison, P. M. Chaikin, R. A. Register, C. J. Hawker, J. Mays, Mixed Lamellar Films: Evolution, Commensurability Effects, and Preferential Defect Formation Macromolecules. ,vol. 33, pp. 80- 88 ,(2000) , 10.1021/MA9912711
Jia-Yu Wang, Ting Xu, Julie M. Leiston-Belanger, Suresh Gupta, Thomas P. Russell, Ion Complexation: A Route to Enhanced Block Copolymer Alignment with Electric Fields Physical Review Letters. ,vol. 96, pp. 128301- ,(2006) , 10.1103/PHYSREVLETT.96.128301
Matthew S. Turner, Michael Rubinstein, Carlos M. Marques, Surface-Induced Lamellar Ordering in a Hexagonal Phase of Diblock Copolymers Macromolecules. ,vol. 27, pp. 4986- 4992 ,(1994) , 10.1021/MA00096A021
J. Ruokolainen, M. Saariaho, O. Ikkala, G. ten Brinke, E. L. Thomas, M. Torkkeli, R. Serimaa, Supramolecular Routes to Hierarchical Structures: Comb-Coil Diblock Copolymers Organized with Two Length Scales Macromolecules. ,vol. 32, pp. 1152- 1158 ,(1999) , 10.1021/MA980189N
J. Q. Zhao, E. M. Pearce, T. K. Kwei, Binary and Ternary Blends of Polystyrene-block-Poly(p-hydroxystyrene) Macromolecules. ,vol. 30, pp. 7119- 7126 ,(1997) , 10.1021/MA970735X
Insun Park, Soojin Park, Hae-Woong Park, Taihyun Chang, Hoichang Yang, Chang Y. Ryu, Unexpected hexagonally perforated layer morphology of PS-b-PMMA block copolymer in supported thin film Macromolecules. ,vol. 39, pp. 315- 318 ,(2006) , 10.1021/MA0515937