作者: D. I. Slovetskii , Yu. A. Mankelevich , S. D. Slovetskii , T. V. Rakhimova
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摘要: A mathematical model was developed for the plasma-chemical pyrolysis of methane, which includes latest data on mechanism and kinetics chemical processes hydrocarbon mixing methane jets with hydrogen heated in an arc plasma torch. The results calculations conversion synthesis acetylene its homologues satisfactorily agree experimental over a wide range parameters process. It shown that is initiated via interaction atomic hydrogen, produced through dissociation intermediate products involving radicals, consumption due to vinylidenecarbene methylenecarbene ground excited states.