Recent advances in nuclear and atomic spectrometric techniques for trace element analysis. A new look at the position of PIXE

作者: Willy Maenhaut

DOI: 10.1016/0168-583X(90)90304-D

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摘要: Abstract The principles, instrumentation and methodological aspects of several nuclear atomic spectrometric techniques for trace element analysis are briefly described. These activation analysis, mainly neutron (NAA), X-ray fluorescence (XRF), including total reflection XRF (TXRF) synchrotron radiation (SR-XRF), emission, absorption spectrometry (AES, AAS AFS), mass spectrometry, in particular inductively coupled plasma (ICP-MS). Recent advances new trends each technique indicated. various intercompared with other particle-induced emission (PIXE), this is done from a number viewpoints, cost the instrument and/or price per sample analyzed, speed type required capability multielement determinations, accuracy detection limits. Particular emphasis placed on assessing present position PIXE, it indicated what types analytical problems PIXE offers significant advantages over techniques.

参考文章(59)
J. A. C. Broekaert, G. Tölg, Recent developments in atomic spectrometry methods for elemental trace determinations Fresenius Journal of Analytical Chemistry. ,vol. 326, pp. 495- 509 ,(1987) , 10.1007/BF00468215
R. Klockenkämper, B. Raith, S. Divoux, B. Gonsior, S. Brüggerhoff, E. Jackwerth, Comparison of different excitation methods for X-ray spectral analysis Fresenius Journal of Analytical Chemistry. ,vol. 326, pp. 105- 117 ,(1987) , 10.1007/BF00468492
P. Wobrauschek, H. Aiginger, Analytical application of total reflection and polarized X-rays Fresenius Journal of Analytical Chemistry. ,vol. 324, pp. 865- 874 ,(1986) , 10.1007/BF00473182
R. Tertian, F. Claisse, Principles of quantitative X-ray fluorescence analysis John Wiley & Sons. ,(1982)
J.P. Willis, XRFS and PIXE: Are they complementary or competitive techniques? Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. ,vol. 35, pp. 378- 387 ,(1988) , 10.1016/0168-583X(88)90299-6
Koen H. Janssens, Fred C. Adams, New trends in elemental analysis using X-ray fluorescence spectrometry Journal of Analytical Atomic Spectrometry. ,vol. 4, pp. 123- 135 ,(1989) , 10.1039/JA9890400123
V.B. Baryshev, G.N. Kulipanov, E.I. Zaytsev, Ya.V. Terekhov, V.I. Kalyuzny, Sensitive X-ray fluorescence analysis of geological samples using synchrotron radiation Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment. ,vol. 261, pp. 279- 282 ,(1987) , 10.1016/0168-9002(87)90616-4
R. Klockenkämper, A. Von Bohlen, B. Wiecken, Quantification in total reflection X-ray fluorescence analysis of microtome sections Spectrochimica Acta Part B: Atomic Spectroscopy. ,vol. 44, pp. 511- 517 ,(1989) , 10.1016/0584-8547(89)80058-8
Y. Yoneda, T. Horiuchi, Optical flats for use in x-ray spectrochemical microanalysis. Review of Scientific Instruments. ,vol. 42, pp. 1069- 1070 ,(1971) , 10.1063/1.1685282