Directional Functionalization of MOF-74 Analogs via Ligand Pre-installation

作者: Liang Hao , Qiming Qiu , Hui Li

DOI: 10.1002/CJOC.201500597

关键词:

摘要: A MOF-74 analog derived from non-DOBDC linkers, Cu(II)-MOF-74-L1, was synthesized and characterized. Based on this, directionanl functionalizations of the hexagonal pore were introduced through well-designed pre-installation ligands. By this strategy, two analogs with hydrophobic hydrophilic surfaces had been achieved by equiping Cl or OH groups respectively proved excellent catalysis luminescent sensing properties. Herein, synthetic strategy functional regulation reported toward development materials.

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