Controlling Stability and Selectivity in the Competing Chlorine and Oxygen Evolution Reaction over Transition Metal Oxide Electrodes

作者: Kai S. Exner

DOI: 10.1002/CELC.201900834

关键词:

摘要: … Here, the selectivity issue and the stability range of a RuO 2 (110) electrode are explored under CER/OER conditions by combining the kinetic description with surface Pourbaix …

参考文章(87)
Zhongnan Xu, John R. Kitchin, Tuning oxide activity through modification of the crystal and electronic structure: from strain to potential polymorphs Physical Chemistry Chemical Physics. ,vol. 17, pp. 28943- 28949 ,(2015) , 10.1039/C5CP04840K
Frank Abild-Pedersen, Computational catalyst screening: Scaling, bond-order and catalysis Catalysis Today. ,vol. 272, pp. 6- 13 ,(2016) , 10.1016/J.CATTOD.2015.08.056
Marc T. M. Koper, Activity volcanoes for the electrocatalysis of homolytic and heterolytic hydrogen evolution Journal of Solid State Electrochemistry. ,vol. 20, pp. 895- 899 ,(2016) , 10.1007/S10008-015-3036-Z
L.J.J. Janssen, L.M.C. Starmans, J.G. Visser, E. Barendrecht, Mechanism of the chlorine evolution on a ruthenium oxide/titanium oxide electrode and on a ruthenium electrode Electrochimica Acta. ,vol. 22, pp. 1093- 1100 ,(1977) , 10.1016/0013-4686(77)80045-5
Kelsey A. Stoerzinger, Liang Qiao, Michael D. Biegalski, Yang Shao-Horn, Orientation-Dependent Oxygen Evolution Activities of Rutile IrO2 and RuO2 Journal of Physical Chemistry Letters. ,vol. 5, pp. 1636- 1641 ,(2014) , 10.1021/JZ500610U
S Trasatti, Electrocatalysis: understanding the success of DSA® Electrochimica Acta. ,vol. 45, pp. 2377- 2385 ,(2000) , 10.1016/S0013-4686(00)00338-8
R.+ Kötz, S Stucki, D Scherson, DM Kolb, None, In-situ identification of RuO4 as the corrosion product during oxygen evolution on ruthenium in acid media Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 172, pp. 211- 219 ,(1984) , 10.1016/0022-0728(84)80187-4
Heine A. Hansen, Venkatasubramanian Viswanathan, Jens K. Nørskov, Unifying Kinetic and Thermodynamic Analysis of 2 e– and 4 e– Reduction of Oxygen on Metal Surfaces Journal of Physical Chemistry C. ,vol. 118, pp. 6706- 6718 ,(2014) , 10.1021/JP4100608
Marc T.M. Koper, Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis Journal of Electroanalytical Chemistry. ,vol. 660, pp. 254- 260 ,(2011) , 10.1016/J.JELECHEM.2010.10.004