Voltammetric determination of traces of Cr(VI) in the flow system in the presence of bipyridyne

作者: M Korolczuk

DOI: 10.1016/S0039-9140(99)00066-1

关键词:

摘要: Abstract The voltammetric method of Cr(VI) determinations in the flow system, based on combination selective accumulation product reduction HMDE and a very sensitive chromium determination presence bipyridine [Z. Gao K.S. Siow, Electroanalysis 8 (1996) 602] is proposed. calibration graphs were linear from 3×10 −9 to −8 5×10 −10 mol l −1 for times 120 600 s, respectively. relative standard deviation (R.S.D.) was 6.5% ( n =5) concentration 1×10 time s. influence foreign ions commonly present water samples presented. Validation made by comparison results analyses tap another electrochemical recovery test river mineral water.

参考文章(10)
Iva Turyan, Daniel Mandler, Selective Determination of Cr(VI) by a Self-Assembled Monolayer-Based Electrode Analytical Chemistry. ,vol. 69, pp. 894- 897 ,(1997) , 10.1021/AC9607525
Catherine Elleouet, François Quentel, Christian Madec, Determination of trace amounts of chromium(VI) in water by electrochemical methods Analytica Chimica Acta. ,vol. 257, pp. 301- 308 ,(1992) , 10.1016/0003-2670(92)85183-7
Dragic V. Vukomanovic, Gary W. vanloon, Kanji Nakatsu, Dick E. Zoutman, Determination of Chromium (VI) and (III) by Adsorptive Stripping Voltammetry with Pyrocatechol Violet Microchemical Journal. ,vol. 57, pp. 86- 95 ,(1997) , 10.1006/MCHJ.1997.1495
Marc Boussemart, Constant M.G. van den Berg, Mohammed Ghaddaf, The determination of the chromium speciation in sea water using catalytic cathodic stripping voltammetry Analytica Chimica Acta. ,vol. 262, pp. 103- 115 ,(1992) , 10.1016/0003-2670(92)80014-X
Andrew M. Dobney, Gillian M. Greenway, On-line determination of chromium by adsorptive cathodic stripping voltammetry Analyst. ,vol. 119, pp. 293- 297 ,(1994) , 10.1039/AN9941900293
Juan C. Vidal, Jos� M. Sanz, Juan R. Castillo, Speciation of Cr(VI)/Cr(III) by electrothermal atomisation AAS after electrodeposition on a L'vov platform Fresenius Journal of Analytical Chemistry. ,vol. 344, pp. 234- 241 ,(1992) , 10.1007/BF00324981
M. A. Ghandour, Salah A. El-Shatoury, Azza M.M. Aly, S. M. Ahmed, Adsorptive cathodic stripping voltammetric determination of hexavalent chromium Analytical Letters. ,vol. 29, pp. 1431- 1445 ,(1996) , 10.1080/00032719608001492
P. Farias, R. Wagener, A. De Luca, E. M. De Souza, VOLTAMMETRIC DETERMINATION OF CR(III) AND CR(VI) IN TROPICAL ESTUARINE WATERS : ADVANTAGES AND LIMITATIONS Croatica Chemica Acta. ,vol. 70, pp. 259- 269 ,(1997)