Nonadiabatic effects in (1~2)1Π–X1Σ+ rovibronic transitions of KRb molecules
作者： S. V. Kozlov , E. A. Pazyuk , A. V. Stolyarov
DOI: 10.1134/S0030400X17110133
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摘要: Numerical simulation of the effect intramolecular electrostatic interactions on redistribution relative intensities in vibrational structure (1 ~ 2)1Π–X1Σ+ rotationally resolved transitions KRb molecule is performed within precision nonadiabatic model coupled channels. It established that mutual perturbation electronically excited states modifies a nontrivial way nodal wavefunction 2)1Π complex, which possible to use for rising efficiency twostep laser synthesis and stabilization ultracold ensembles molecules ground electronic state.
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