Synthesis of amphoteric starch-based grafting flocculants for flocculation of both positively and negatively charged colloidal contaminants from water

作者: Zhen Yang , Hu Wu , Bo Yuan , Mu Huang , Hu Yang

DOI: 10.1016/J.CEJ.2014.01.083

关键词:

摘要: Contaminants in real water are normally complicated. Surface charges of suspended colloidal particles can be either negative or positive. In this work, a series amphoteric starch-based grafting flocculants (3-chloro-2-hydroxypropyl trimethyl ammonium chloride modified starch-graft-poly(acrylamide-co-acrylic acid)) denoted as SCPAMPAA were successfully synthesized with different ratios and used for the removal charged contaminants from water. Various exhibited remarkably flocculation performance obeyed diverse mechanisms due to differences their structural characteristics. Therefore, precise control molecular structure is great significance obtain desired performance. To provide practically operational feasibility preparation predicted flocculant, quantitative mathematical correlation between recipe features derived. The final well-designed flocculant demonstrated high aspects optimal dosage, window pH sensitivity both negatively positively targeted wastewater.

参考文章(46)
Luminita Ghimici, Marieta Nichifor, Novel biodegradable flocculanting agents based on cationic amphiphilic polysaccharides Bioresource Technology. ,vol. 101, pp. 8549- 8554 ,(2010) , 10.1016/J.BIORTECH.2010.06.049
Sumit Mishra, Ankita Mukul, Gautam Sen, Usha Jha, Microwave assisted synthesis of polyacrylamide grafted starch (St-g-PAM) and its applicability as flocculant for water treatment. International Journal of Biological Macromolecules. ,vol. 48, pp. 106- 111 ,(2011) , 10.1016/J.IJBIOMAC.2010.10.004
SK Akbar Ali, Ram Prakash Singh, None, An investigation of the flocculation characteristics of polyacrylamide‐grafted chitosan Journal of Applied Polymer Science. ,vol. 114, pp. 2410- 2414 ,(2009) , 10.1002/APP.30798
J. Beltrán-Heredia, J. Sánchez-Martín, M.A. Dávila-Acedo, Optimization of the synthesis of a new coagulant from a tannin extract Journal of Hazardous Materials. ,vol. 186, pp. 1704- 1712 ,(2011) , 10.1016/J.JHAZMAT.2010.12.075
Xi-Guang Chen, Hyun-Jin Park, Chemical characteristics of O-carboxymethyl chitosans related to the preparation conditions Carbohydrate Polymers. ,vol. 53, pp. 355- 359 ,(2003) , 10.1016/S0144-8617(03)00051-1
Ali Pourjavadi, Seyed Mahmoud Fakoorpoor, Seyed Hassan Hosseini, Novel cationic-modified salep as an efficient flocculating agent for settling of cement slurries Carbohydrate Polymers. ,vol. 93, pp. 506- 511 ,(2013) , 10.1016/J.CARBPOL.2012.12.049
A. Hebeish, A. Higazy, A. El-Shafei, S. Sharaf, Synthesis of carboxymethyl cellulose (CMC) and starch-based hybrids and their applications in flocculation and sizing Carbohydrate Polymers. ,vol. 79, pp. 60- 69 ,(2010) , 10.1016/J.CARBPOL.2009.07.022
H. Bulbul Sonmez, B. F. Senkal, N. Bicak, Poly(acrylamide) grafts on spherical bead polymers for extremely selective removal of mercuric ions from aqueous solutions Journal of Polymer Science Part A. ,vol. 40, pp. 3068- 3078 ,(2002) , 10.1002/POLA.10392