A STRUCTURAL INTERPRETATION OF THE ACIDITY OF GROUPS ASSOCIATED WITH THE HEMES OF HEMOGLOBIN AND HEMOGLOBIN DERIVATIVES
作者： Charles D. Coryell , Linus Pauling
DOI: 10.1016/S0021-9258(19)56225-1
关键词:
摘要: Since the discovery by Bohr and coworkers in 1904 of effect acidity on oxygen equilibrium hemoglobin, there have been a large number investigations directed towards clarification physicochemical relationships acid groups with hemes hemoglobin its derivatives. It is purpose this paper to analyze modern quantitative data, including those for ferrihemoglobin (methemoglobin), order throw new light general problem, establish ionization constant an group previously unrecognized, give structural interpretation shifts pK caused changing chemical environment.
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