Pyrrole Hydrogenation over Rh(111) and Pt(111) Single-Crystal Surfaces and Hydrogenation Promotion Mediated by 1-Methylpyrrole: A Kinetic and Sum-Frequency Generation Vibrational Spectroscopy Study
作者： Christopher J. Kliewer , Marco Bieri , Gabor A. Somorjai
DOI: 10.1021/JP8019123
关键词:
摘要: Pyrrole Hydrogenation over Rh(111) and Pt(111) Single-Crystal Surfaces Promotion Mediated by 1-Methylpyrrole: A Kinetic Sum- Frequency Generation Vibrational Spectroscopy Study Christopher J. Kliewer, Marco Bieri Gabor A. Somorjai* Department of Chemistry, University California, Berkeley, California 94720, Materials Sciences Division, Lawrence Berkeley National Laboratory, 94720 E-mail: somorjai@socrates.berkeley.edu TITLE RUNNING HEAD: hydrogenation RECEIVED DATE (to be automatically inserted after your manuscript is accepted if required according to the journal that you are submitting paper to) CORRESPONDING AUTHOR FOOTNOTE: Somorjai, Tel: 510-642-4053. Fax: 510-643- 9668. somorjai@socrates.berkeley.edu. ABSTRACT. Sum frequency generation surface vibrational spectroscopy kinetic measurements using gas chromatography have been used study adsorption pyrrole both single-crystal surfaces at Torr pressures (3 pyrrole, 30 H 2 ) form pyrrolidine minor product butylamine. Over 298K it was found adsorbs in an upright geometry cleaving N-H bond bind through nitrogen evidenced SFG data.
acs.org
core.ac.uk
osti.gov
sci-hub.se 参考文章(38)
S.D. Jackson, H. Hardy, G.J. Kelly, L.A. Shaw, The effect of co-adsorbates on activity/selectivity in the hydrogenation of aromatic alkynes Studies in Surface Science and Catalysis. ,vol. 108, pp. 305- 311 ,(1997) , 10.1016/S0167-2991(97)80918-4
G. Tourillon, S. Raaen, T.A. Skotheim, M. Sagurton, R. Garrett, G.P. Williams, A near edge X-ray absorption fine structure study of the adsorption of pyrrole and N-methylpyrrole on Pt(111): Orientation and dissociation of the adsorbed molecules Surface Science. ,vol. 184, ,(1987) , 10.1016/S0039-6028(87)80261-3
László Hegedüs, Tibor Máthé, Antal Tungler, Erratum to: Hydrogenation of pyrrole derivatives. Part IV. Hydrogenation of 1-methylpyrrole, Appl. Catal. 152 (1997) 143–151 (APCATA 3708) Applied Catalysis A: General. ,vol. 161, pp. 283- ,(1997) , 10.1016/S0926-860X(97)00239-1
P. S. Weiss, D. M. Eigler, Site dependence of the apparent shape of a molecule in scanning tunneling micoscope images: Benzene on Pt{111} Physical Review Letters. ,vol. 71, pp. 3139- 3142 ,(1993) , 10.1103/PHYSREVLETT.71.3139
Kaitlin M. Bratlie, Christopher J. Kliewer, Gabor A. Somorjai, Structure Effects of Benzene Hydrogenation Studied with Sum Frequency Generation Vibrational Spectroscopy and Kinetics on Pt(111) and Pt(100) Single-Crystal Surfaces Journal of Physical Chemistry B. ,vol. 110, pp. 17925- 17930 ,(2006) , 10.1021/JP062623Q
K. Y. Kung, P. Chen, F. Wei, G. Rupprechter, Y. R. Shen, G. A. Somorjai, Ultrahigh vacuum high-pressure reaction system for 2-infrared 1-visible sum frequency generation studies Review of Scientific Instruments. ,vol. 72, pp. 1806- 1809 ,(2001) , 10.1063/1.1329902
E. B. Maxted, A. G. Walker, 217. Studies in the detoxication of catalyst poisons. Part VII. The self-poisoning effect in the hydrogenation of pyridine Journal of the Chemical Society (Resumed). ,vol. 10, pp. 1093- 1097 ,(1948) , 10.1039/JR9480001093
László Hegedu˝s, Tibor Máthé, Antal Tungler, Hydrogenation of pyrrole derivatives I. Hydrogenations over palladium Applied Catalysis A-general. ,vol. 143, pp. 309- 316 ,(1996) , 10.1016/0926-860X(96)00094-4
László Hegedüs, Tibor Máthé, Antal Tungler, Hydrogenation of pyrrole derivatives. II. Hydrogenations over supported noble metal catalysts Applied Catalysis A: General. ,vol. 147, pp. 407- 414 ,(1996) , 10.1016/S0926-860X(96)00217-7
A. Mellouki, J. Liévin, M. Herman, The vibrational spectrum of pyrrole (C4H5N) and furan (C4H4O) in the gas phase principles and practice of constraint programming. ,vol. 271, pp. 239- 266 ,(2001) , 10.1016/S0301-0104(01)00447-5