Analysis of manganese particulates from automotive decomposition of methylcyclopentadienyl manganese tricarbonyl

作者: C Colmenares , Steven Deutsch , Cheryl Evans , A.J Nelson , Louis J Terminello

DOI: 10.1016/S0169-4332(99)00261-5

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摘要: Abstract Particulates have been collected and analyzed from automotive vehicles operating on fuel containing the organometallic antiknock additive methylcyclopentadienyl manganese tricarbonyl. Electron spectroscopy for chemical analysis L-edge X-ray absorption were used to study identify species present in these emitted particulates. Results show that respirable size particulates with a mass median aerodynamic diameter of 2.5 μm or less (PM2.5) vehicle exhaust contain primarily form phosphate and/or sulfate.

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