Syntheses of macrocyclic enzyme models. 7. Octopus cyclophanes having L-aspartate residues as novel water-soluble hosts; aggregation behavior and induced-fit molecular recognition
作者： Yukito Murakami , Junichi Kikuchi , Teruhisa Ohno , Osamu Hayashida , Masayo Kojima
DOI: 10.1021/JA00177A031
关键词:
摘要: We now prepared octopus cyclophanes each having L-aspartate residues, 1 and 2. The chiral molecular components were introduced as connector units, interposed between a tetraaza-[3.3.3.3] paracyclophane skeleton an body hydrocarbon branches hydrophobic arms. In this article, we report on their aggregation behavior unique guest-binding in aqueous media with emphasis the first successful observations of dynamic features induced-fit host-guest complexation
acs.org
sci-hub.se 参考文章(0)