Model-free kinetics

摘要: The paper presents the model-free kinetic approach in the context of the traditional kinetic description based on the kinetic triplet, A, E, and f (α) or g (α). A physical meaning and interpretability of the triplet are considered. It is argued that the experimental values of f (α) or g (α) and A are unlikely to be interpretable in the respective terms of the reaction mechanism and of the vibrational frequency of the activated complex. The traditional kinetic description needs these values for making kinetic predictions. Interpretations are most …