Chelating alkoxy-N-heterocyclic carbene complexes of silver and copper

作者: Polly L. Arnold , Andrew C. Scarisbrick , Alexander J. Blake , Claire Wilson

DOI: 10.1039/B107855K

关键词:

摘要: Incorporation of an alkoxide functional group into N-heterocyclic carbene (NHC) ligand allows the synthesis first anionic NHC chelating ligands, which react to give neutral, molecular silver(I) complex, and a copper(I) derivative containing non-macrocyclic, square planar Cu(I) centres.

参考文章(15)
Wolfgang A. Herrmann, Claus-Peter Reisinger, Michael Spiegler, Chelating N-heterocyclic carbene ligands in palladium-catalyzed heck-type reactions Journal of Organometallic Chemistry. ,vol. 557, pp. 93- 96 ,(1998) , 10.1016/S0022-328X(97)00736-5
Arran A. D. Tulloch, Andreas A. Danopoulos, Sven Kleinhenz, Mark E. Light, Michael B. Hursthouse, Graham Eastham, Structural Diversity in Pyridine-N-Functionalized Carbene Copper(I) Complexes Organometallics. ,vol. 20, pp. 2027- 2031 ,(2001) , 10.1021/OM010014T
Harrison M. J. Wang, Ivan J. B. Lin, FACILE SYNTHESIS OF SILVER(I)-CARBENE COMPLEXES. USEFUL CARBENE TRANSFER AGENTS Organometallics. ,vol. 17, pp. 972- 975 ,(1998) , 10.1021/OM9709704
Christian Boehme, Gernot Frenking, N-Heterocyclic Carbene, Silylene, and Germylene Complexes of MCl (M = Cu, Ag, Au). A Theoretical Study1 Organometallics. ,vol. 17, pp. 5801- 5809 ,(1998) , 10.1021/OM980394R
Misato Shinoura, Satoru Kita, Masaaki Ohba, Hisashi Ōkawa, Hideki Furutachi, Masatatsu Suzuki, A Heterodinuclear CoIICuI Complex with Co(salen) in a Macrocyclic Framework. Oxygenation Studies in Comparison with Analogous CuIICuI and CoIIPbII Complexes Inorganic Chemistry. ,vol. 39, pp. 4520- 4526 ,(2000) , 10.1021/IC000305E
Holger Glas, Eberhardt Herdtweck, Michael Spiegler, Anna-Katharina Pleier, Werner R Thiel, A simple access to palladium complexes of functionalized heterocyclic carbenes Journal of Organometallic Chemistry. ,vol. 626, pp. 100- 105 ,(2001) , 10.1016/S0022-328X(01)00655-6
Alison M Magill, David S McGuinness, Kingsley J Cavell, George J.P Britovsek, Vernon C Gibson, Andrew J.P White, David J Williams, Allan H White, Brian W Skelton, Palladium(II) complexes containing mono-, bi- and tridentate carbene ligands. Synthesis, characterisation and application as catalysts in CC coupling reactions Journal of Organometallic Chemistry. ,vol. 617, pp. 546- 560 ,(2001) , 10.1016/S0022-328X(00)00720-8
Richard E. Douthwaite, Malcolm L. H. Green, Peter J. Silcock, Pedro T. Gomes, Nickel(II) cis- and trans-Dimethyl Complexes of Di-N-heterocyclic Carbenes Organometallics. ,vol. 20, pp. 2611- 2615 ,(2001) , 10.1021/OM010139Y
David J. Nielsen, Kingsley J. Cavell, Brian W. Skelton, Allan H. White, Competition between Carbene and Pseudo η3-Allyl Bonding Modes in a Palladium(II) Complex of a Functionalized Bis(imidazolium) Ligand Organometallics. ,vol. 20, pp. 995- 1000 ,(2001) , 10.1021/OM000905L
Anthony J. Arduengo, H. V. Rasika Dias, Joseph C. Calabrese, Fredric Davidson, Homoleptic carbene-silver(I) and carbene-copper(I) complexes Organometallics. ,vol. 12, pp. 3405- 3409 ,(1993) , 10.1021/OM00033A009