Branching ratios of electronic quenching of atomic sulfur S(3p34p 3PJ) by collisions with N2
作者： Daigo Kawabata , Shogo Tendo , Yuki Tanimoto , Rintaro Fukami , Hiroshi Kohguchi
DOI: 10.1016/J.CPLETT.2020.137730
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摘要: Abstract Atomic sulfur S ( 3 p 4 P ) was generated in the photolysis of OCS at 248 nm and exited to state by ultraviolet two-photon absorption 308 nm. Transfer from 4s infrared radiation and/or collisions with ambient gases followed vacuum (VUV) fluorescence via → transition 180 nm. The time-resolved VUV intensity recorded varying pressures N2. Kinetic analyses have given not only overall rate coefficient for quenching N2 but also branching ratio state.
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