The influence of reaction parameters on characteristics of pyrolysis oils from waste high impact polystyrene and acrylonitrile- butadiene-styrene using a fluidized bed reactor
作者： Su-Hwa Jung , Seon-Jin Kim , Joo-Sik Kim
DOI: 10.1016/J.FUPROC.2013.05.004
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摘要: Abstract The aim of this study was to produce pyrolysis oils from waste high impact polystyrene (HIPS) and acrylonitrile–butadiene–styrene (ABS) in a plant equipped with fluidized bed reactor. influence various reaction parameters, such as temperature, feed rate the kind fluidizing medium, investigated. maximum oil yields were about 87 wt.% (474 °C) for HIPS 84 wt.% (525 °C) ABS. A higher use product gas medium favorable production. produced consisted chiefly toluene, ethylbenzene, styrene, cumene, α-methylstyrene styrene dimers they appeared be usable directly fuel or chemical source. Main compounds ABS similar those obtained HIPS, except nitrogen-containing compounds. In nitrogen mass balance products, most concentrated content 6.5–7.1 wt.%. seemed require further treatment its
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sci-hub.se 参考文章(23)
M Blazsó, Zs Czégény, Cs Csoma, Pyrolysis and debromination of flame retarded polymers of electronic scrap studied by analytical pyrolysis Journal of Analytical and Applied Pyrolysis. ,vol. 64, pp. 249- 261 ,(2002) , 10.1016/S0165-2370(02)00035-9
William J. Hall, Paul T. Williams, Removal of organobromine compounds from the pyrolysis oils of flame retarded plastics using zeolite catalysts Journal of Analytical and Applied Pyrolysis. ,vol. 81, pp. 139- 147 ,(2008) , 10.1016/J.JAAP.2007.09.008
William J. Hall, Paul T. Williams, PYROLYSIS OF BROMINATED FEEDSTOCK PLASTIC IN A FLUIDISED BED REACTOR Journal of Analytical and Applied Pyrolysis. ,vol. 77, pp. 75- 82 ,(2006) , 10.1016/J.JAAP.2006.01.006
Eleanor E. Storrs, Gas phase chromatography. Vol. 2 Microchemical Journal. ,vol. 8, pp. 324- 325 ,(1964) , 10.1016/0026-265X(64)90122-5
Rudolf Kaiser, Gas phase chromatography Butterworths. ,(1995) , 10.1007/978-1-4684-8291-1
O. Levenspiel, K. Daizo, Fluidization engineering, 2nd edition Stoneham, MA (United States); Butterworth Publishers. ,(1991)
Nona Merry M. Mitan, Mihai Brebu, Thallada Bhaskar, Akinori Muto, Yusaku Sakata, Individual and simultaneous degradation of brominated high impact polystyrene and brominated acrylonitrile-butadiene-styrene and removal of heteroelements (Br, N, and O) from degradation oil by multiphase catalytic systems Journal of Material Cycles and Waste Management. ,vol. 9, pp. 56- 61 ,(2007) , 10.1007/S10163-006-0159-4
Mihai Brebu, Emma Jakab, Yusaku Sakata, Effect of flame retardants and Sb2O3 synergist on the thermal decomposition of high-impact polystyrene and on its debromination by ammonia treatment Journal of Analytical and Applied Pyrolysis. ,vol. 79, pp. 346- 352 ,(2007) , 10.1016/J.JAAP.2007.02.003
Md.Azhar Uddin, Thallada Bhaskar, Jun Kaneko, Akinori Muto, Yusaku Sakata, Toshiki Matsui, Dehydrohalogenation during pyrolysis of brominated flame retardant containing high impact polystyrene (HIPS-Br) mixed with polyvinylchloride (PVC) ☆ Fuel. ,vol. 81, pp. 1819- 1825 ,(2002) , 10.1016/S0016-2361(02)00109-6