Bromide–chloride exchange between alkyl halides and metal halide salts under phase transfer conditions

作者: Y. Sasson , M. Weiss , A. Loupy , G. Bram , C. Pardo

DOI: 10.1039/C39860001250

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摘要: The equilibrium position of the phase transfer catalysed exchange reaction RCl + MBr ⇌ RBr MCl where R = primary alkyl group and M Li, Na, K, Ca is strongly dependent on nature metal cation amount water present in mixture; this has been applied synthetic use both directions.

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