A versatile low temperature solid-state synthesis of vanadium nitride (VN) via a “guanidinium-route”: experimental and theoretical studies from the key-intermediate to the final product
作者： Eugenio Furtado de Souza , Carlos Alberto Chagas , Teodorico C. Ramalho , Ricardo Bicca de Alencastro
DOI: 10.1039/C2DT31614E
关键词:
摘要: An easy and efficient method (“guanidinium route”) to synthesize vanadium nitride (VN) is evaluated in this paper. Initially, ammonium m-vanadate was mixed with guanidinium carbonate, producing an important intermediate, (GmV), through a solid-state reaction. GmV decomposed as function of the temperature studied TGA, DRX, FT-Infrared, Temperature-Programmed Surface Reaction (TPSR) DFT. We show that transformed into bulk crystalline VN below 800 °C. XPS, periodic DFT calculations, elemental analyses surface not carbon-free.
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