Nature of the bias-dependent symmetry reduction of iron phthalocyanine on Cu(111)

作者: Olesia Snezhkova , Johann Lüder , Alissa Wiengarten , Shiri R. Burema , Felix Bischoff

DOI: 10.1103/PHYSREVB.92.075428

关键词:

摘要: Subtle changes in the geometric and electronic properties of supported molecules, with a potential impact on functioning molecular devices, can typically be imaged by scanning probe microscopy, but their exact origin nature often remain unclear. Here we show explicitly that symmetry reduction iron phthalocyanine upon adsorption Cu(111) observed not only tunneling also core-level spectroscopy, it is related to nonisotropic charge transfer into two principal axes, combination topographic influences.

参考文章(72)
Chong-an Di, Fengjiao Zhang, Daoben Zhu, Multi-functional integration of organic field-effect transistors (OFETs): advances and perspectives. Advanced Materials. ,vol. 25, pp. 313- 330 ,(2013) , 10.1002/ADMA.201201502
Gema de la Torre, Giovanni Bottari, Michael Sekita, Anita Hausmann, Dirk M. Guldi, Tomás Torres, A voyage into the synthesis and photophysics of homo- and heterobinuclear ensembles of phthalocyanines and porphyrins. Chemical Society Reviews. ,vol. 42, pp. 8049- 8105 ,(2013) , 10.1039/C3CS60140D
Mário J. F. Calvete, Mónica Silva, Mariette M. Pereira, Hugh D. Burrows, Inorganic helping organic: recent advances in catalytic heterogeneous oxidations by immobilised tetrapyrrolic macrocycles in micro and mesoporous supports RSC Advances. ,vol. 3, pp. 22774- 22789 ,(2013) , 10.1039/C3RA44038A
Ben Warner, Fadi El Hallak, Henning Prüser, John Sharp, Mats Persson, Andrew J. Fisher, Cyrus F. Hirjibehedin, Tunable magnetoresistance in an asymmetrically coupled single-molecule junction Nature Nanotechnology. ,vol. 10, pp. 259- 263 ,(2015) , 10.1038/NNANO.2014.326
Juan Liu, Chao Li, Xiaoqing Liu, Yan Lu, Feifei Xiang, Xuelei Qiao, Yingxiang Cai, Zhongping Wang, Sanqiu Liu, Li Wang, Positioning and switching phthalocyanine molecules on a Cu(100) surface at room temperature. ACS Nano. ,vol. 8, pp. 12734- 12740 ,(2014) , 10.1021/NN5058535
A. Mugarza, N. Lorente, P. Ordejón, C. Krull, S. Stepanow, M.-L. Bocquet, J. Fraxedas, G. Ceballos, P. Gambardella, Orbital specific chirality and homochiral self-assembly of achiral molecules induced by charge transfer and spontaneous symmetry breaking. Physical Review Letters. ,vol. 105, pp. 115702- ,(2010) , 10.1103/PHYSREVLETT.105.115702
Willi Auwärter, David Écija, Florian Klappenberger, Johannes V. Barth, Porphyrins at interfaces Nature Chemistry. ,vol. 7, pp. 105- 120 ,(2015) , 10.1038/NCHEM.2159
Alissa Wiengarten, Knud Seufert, Willi Auwärter, David Ecija, Katharina Diller, Francesco Allegretti, Felix Bischoff, Sybille Fischer, David A. Duncan, Anthoula C. Papageorgiou, Florian Klappenberger, Robert G. Acres, Thien H. Ngo, Johannes V. Barth, Surface-assisted dehydrogenative homocoupling of porphine molecules. Journal of the American Chemical Society. ,vol. 136, pp. 9346- 9354 ,(2014) , 10.1021/JA501680N
Sebastian Stepanow, Alberto Lodi Rizzini, Cornelius Krull, Jerald Kavich, Julio C Cezar, Flora Yakhou-Harris, Polina M Sheverdyaeva, Paolo Moras, Carlo Carbone, Gustavo Ceballos, Aitor Mugarza, Pietro Gambardella, None, Spin tuning of electron-doped metal-phthalocyanine layers. Journal of the American Chemical Society. ,vol. 136, pp. 5451- 5459 ,(2014) , 10.1021/JA501204Q
Benjamin Stadtmüller, Ingo Kröger, Friedrich Reinert, Christian Kumpf, Submonolayer growth of CuPc on noble metal surfaces Physical Review B. ,vol. 83, pp. 085416- ,(2011) , 10.1103/PHYSREVB.83.085416