Binuclear Metal Complexes. XLIV. Crystal Structures and Magnetic Properties of Alkoxo-oxygen Bridged Binuclear Copper(II) Complexes with 2-[2-(Dialkylamino)ethylthio]ethanol
作者： Masahiro Mikuriya , Hisashi Okawa , Sigeo Kida
DOI: 10.1246/BCSJ.55.1086
关键词:
摘要: Six binuclear copper(II) complexes with 2-[2-(dialkylamino)ethylthio]ethanol, Cu2{R2N(CH2)2S(CH2)2O}2X2 (abbreviated as Cu(R-nso)X, where R=CH3, C2H5, n-C3H7, n-C4H9; X=Cl, Br), were characterized by magnetic susceptibility (80–300 K). The temperature dependence of the susceptibilities Cu(C2H5-nso)Cl and Cu(n-C4H9-nso)Cl can be interpreted Bleaney-Bowers equation based on a structure, while data other do not obey equation. X-Ray structure analyses have revealed that structures all consist discrete alkoxo-bridged units, coordination geometry each copper atom is distorted square pyramid two oxygen, one sulfur chlorine or bromine atoms in basal plane nitrogen apical position. major structural difference corresponding to different behaviors was attributed conformations chelate ring (Remark: Graphics omitted.).
csj.jp参考文章(16)
Naohide Matsumoto, Sigeo Kida, Ikuhiko Ueda, THE MOLECULAR STRUCTURE OF THE ALKOXO-OXYGEN BRIDGED BINUCLEAR COPPER (II) COMPLEX, [Cu2{(CH3)2N(CH2)3NH(CH2)2O}2(CH3OH)2](ClO4)2 Journal of Coordination Chemistry. ,vol. 9, pp. 133- 137 ,(1979) , 10.1080/00958977908076517
Derek J. Hodgson, The Structural and Magnetic Properties of First-Row Transition-Metal Dimers Containing Hydroxo, Substituted Hydroxo, and Halogen Bridges Progress in Inorganic Chemistry. ,vol. 7, pp. 173- 241 ,(2007) , 10.1002/9780470166208.CH4
Wolfgang Haase, Kristall- und Molekülstrukturen von Halogeno(2-diäthylamino-äthanolato)kupfer(II)-Komplexen (Halogen: Chlor und Brom) Chemische Berichte. ,vol. 106, pp. 3132- 3148 ,(1973) , 10.1002/CBER.19731061006
Masahiro Mikuriya, Hisashi Okawa, Sigeo Kida, Binuclear Metal Complexes. XLI. Crystal Structure and Unusual Magnetic Property of Isothiocyanato{2-[2-(dimethylamino)ethylthio]ethanolato}copper(II) Bulletin of the Chemical Society of Japan. ,vol. 54, pp. 2979- 2982 ,(1981) , 10.1246/BCSJ.54.2979
Masahiro Mikuriya, Hisashi Okawa, Sigeo Kida, Binuclear Metal Complexes. XXXIII. Synthesis, Structure, Spectra, and Magnetism of Binuclear Copper(II) Complexes with 2-[2-(Dialkylamino)ethylthio]ethanol Bulletin of the Chemical Society of Japan. ,vol. 53, pp. 2871- 2877 ,(1980) , 10.1246/BCSJ.53.2871
Ray J. Butcher, Ekk. Sinn, Relation Between Magnetic, Spectroscopic, and Structural Properties of Bis[chloro(N-isopropyl-2-hydroxybenzylidene)aminato-μ-O-copper(II)] and Bis(N-isopropyl-2-hydroxybenzylideneaminato)copper(II) Inorganic Chemistry. ,vol. 15, pp. 1604- 1608 ,(1976) , 10.1021/IC50161A026
Michinobu Kato, Yoneichiro Muto, Hans B. Jonassen, Kyoko Imai, Akiko Harano, Magnetic Moments and d–d Bands of N-n-Propanolsalicylaldiminato-copper(II) Bulletin of the Chemical Society of Japan. ,vol. 41, pp. 1864- 1870 ,(1968) , 10.1246/BCSJ.41.1864
Robert F. Stewart, Ernest R. Davidson, William T. Simpson, Coherent X‐Ray Scattering for the Hydrogen Atom in the Hydrogen Molecule Journal of Chemical Physics. ,vol. 42, pp. 3175- 3187 ,(1965) , 10.1063/1.1696397
L. Merz, W. Haase, The crystal structures of two modifications of isocyanato(2‐dipropylaminoethanolato)copper(II) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 34, pp. 2128- 2133 ,(1978) , 10.1107/S0567740878007566
R. Mergehenn, W. Haase, R. Allmann, Kristallstrukturen von Chloro‐ und γ‐Bromo‐(2‐dibutylaminoäthanolato)‐kupfer(II) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 31, pp. 1847- 1853 ,(1975) , 10.1107/S0567740875006358