Hydrothermal synthesis and structural studies of novel 2-D lanthanide coordination polymers with phthalic acid
作者： Yonghong Wan , Linpei Jin , Kezhi Wang , Liping Zhang , Xiangjun Zheng
DOI: 10.1039/B206280C
关键词:
摘要: This paper presents four lanthanide coordination polymers, [Ln2(BDC)3(H2O)]n (Ln = La, 1; Ln = Eu, 2; Ln = Tb, 3; BDC = 1,2-benzenedicarboxylate) and [Yb4(BDC)6(H2O)2]n (4) prepared by the hydrothermal technique. They are all 2-D infinite structures with BDC anions connecting adjacent metal ions. In complex 1, La(III) ions eight- nine-coordinated, coplanar in structure. complexes 2 3, Eu(III) Tb(III) also but they distributed a wave-like network. 4, Yb(III) have different numbers (6, 7, 8 9), which rarely found one complex. Both arrangement of Ln atoms these polymers show contraction. complexes, oxygen take part Ln(III) ions, adopting tetra-, penta- hexadentate modes for phthalate anions. The luminescent properties been investigated results explanation chemical environment ion consistent X-ray analysis.
rsc.org
unirioja.es
irgrid.ac.cn参考文章(22)
Song Han, Ruyi Yang, Xiaoying Huang, Jing Li, Long Pan, Nengwu Zheng, Yonggang Wu, Synthesis, Characterization and Structural Transformation of A Condensed Rare Earth Metal Coordination Polymer Inorganic Chemistry. ,vol. 40, pp. 828- 830 ,(2001) , 10.1021/IC0007254
Theresa M. Reineke, Mohamed Eddaoudi, Michael Fehr, Douglas Kelley, O. M. Yaghi, From Condensed Lanthanide Coordination Solids to Microporous Frameworks Having Accessible Metal Sites Journal of the American Chemical Society. ,vol. 121, pp. 1651- 1657 ,(1999) , 10.1021/JA983577D
Saleh K. Shakhatreh, Evangelos G. Bakalbassis, Irene. Bruedgam, Hans. Hartl, Jerzy. Mrozinski, Constantinos A. Tsipis, Strong ferromagnetism between copper(II) ions separated by 6.7 Å in a new phthalato-bridged copper(II) binuclear complex Inorganic Chemistry. ,vol. 30, pp. 2801- 2806 ,(1991) , 10.1021/IC00013A018
José Luis Lucas Vaz, Gérard Duc, Michelle Petit-Ramel, René Faure, Olivier Vittori, Cd(II) complexes with phthalic acids: solution study and crystal structure of cadmium(II) phthalate hydrate Canadian Journal of Chemistry. ,vol. 74, pp. 359- 364 ,(1996) , 10.1139/V96-040
Zhong-Le Huang, Marc Drillon, Norberto Masciocchi, Angelo Sironi, Jing-Tai Zhao, Pierre Rabu, Pierre Panissod, Ab-Initio XRPD Crystal Structure and Giant Hysteretic Effect (Hc = 5.9 T) of a New Hybrid Terephthalate-Based Cobalt(II) Magnet† Chemistry of Materials. ,vol. 12, pp. 2805- 2812 ,(2000) , 10.1021/CM000386C
P. Caro, O.K. Moune, E. Antic-Fidancev, M. Lemaitre-Blaise, Vibronic optical transitions in inorganic and organic rare earth materials Journal of the Less Common Metals. ,vol. 112, pp. 153- 173 ,(1985) , 10.1016/0022-5088(85)90022-0
Samuel M-F. Lo, Stephen S-Y. Chui, Lai-Yung Shek, Zhenyang Lin, Xi Xiang Zhang, Ge-hei Wen, Ian D. Williams, Solvothermal Synthesis of a Stable Coordination Polymer with Copper-I−Copper-II Dimer Units: [Cu4{1,4-C6H4(COO)2}3(4,4‘-bipy)2]n Journal of the American Chemical Society. ,vol. 122, pp. 6293- 6294 ,(2000) , 10.1021/JA000416C
Rachel C. Squire, Sheila M. J. Aubin, Kirsten Folting, William E. Streib, George Christou, David N. Hendrickson, Octadecanuclearity in Manganese Carboxylate Chemistry: Preparation and Properties of K4[Mn18O16(O2CPh)22(phth)2(H2O)4].cntdot.10MeCN Inorganic Chemistry. ,vol. 34, pp. 6463- 6471 ,(1995) , 10.1021/IC00130A011
Svetlana G Baca, Yurii A Simonov, Nicolae V Gerbeleu, Maria Gdaniec, Paulina N Bourosh, Grigore A Timco, Synthesis and X-ray diffraction study of Zn(II) complexes with o-phthalic acid and aromatic amines ☆ Polyhedron. ,vol. 20, pp. 831- 837 ,(2001) , 10.1016/S0277-5387(01)00698-2
Zhong-Ning Chen, Hua-Xin Zhang, Kai-Bei Yu, Bei-Sheng Kang, Hu Cai, Cheng-Yong Su, Tian-Wei Wang, Zhong-Lin Lu, 3D Extended Supramolecular Structures via H-Bonded Linkages of 2D Sheetlike or 1D Zigzag Coordination Polymers. Inorganic Chemistry. ,vol. 37, pp. 4775- 4781 ,(1998) , 10.1021/IC980116K