Copper-mediated cyanotrifluoromethylation of styrenes using the Togni reagent.
作者： Nadia O. Ilchenko , Pär G. Janson , Kálmán J. Szabó
DOI: 10.1021/JO401831T
关键词:
摘要: Styrenes with an electron-deficient double bond undergo cyanotrifluoromethylation a trifluoromethylated hypervalent iodine reagent in the presence of CuCN. The reaction proceeds under mild con ...
acs.org
sci-hub.se 参考文章(31)
Andrew T. Parsons, Stephen L. Buchwald, Organic chemistry: A radical approach to diversity Nature. ,vol. 480, pp. 184- 185 ,(2011) , 10.1038/480184A
Xi Wang, Yuxuan Ye, Songnan Zhang, Jiajie Feng, Yan Xu, Yan Zhang, Jianbo Wang, Copper-catalyzed C(sp3)-C(sp3) bond formation using a hypervalent iodine reagent: an efficient allylic trifluoromethylation. Journal of the American Chemical Society. ,vol. 133, pp. 16410- 16413 ,(2011) , 10.1021/JA207775A
Pär G. Janson, Ibrahim Ghoneim, Nadia O. Ilchenko, Kálmán J. Szabó, Electrophilic Trifluoromethylation by Copper-Catalyzed Addition of CF3-Transfer Reagents to Alkenes and Alkynes Organic Letters. ,vol. 14, pp. 2882- 2885 ,(2012) , 10.1021/OL3011419
K. Muller, C. Faeh, F. Diederich, Fluorine in Pharmaceuticals: Looking Beyond Intuition. Science. ,vol. 317, pp. 1881- 1886 ,(2007) , 10.1126/SCIENCE.1131943
David S. Laitar, Peter Müller, Joseph P. Sadighi, Efficient homogeneous catalysis in the reduction of CO2 to CO. Journal of the American Chemical Society. ,vol. 127, pp. 17196- 17197 ,(2005) , 10.1021/JA0566679
Teruo Umemoto, Electrophilic Perfluoroalkylating Agents. Chemical Reviews. ,vol. 96, pp. 1757- 1778 ,(1996) , 10.1021/CR941149U
Nadia O. Ilchenko, Pär G. Janson, Kálmán J. Szabó, Copper-mediated C–H trifluoromethylation of quinones Chemical Communications. ,vol. 49, pp. 6614- 6616 ,(2013) , 10.1039/C3CC43357A
Zhiqiang Weng, Huaifeng Li, Weiming He, Liang-Feng Yao, Jianwei Tan, Jinfa Chen, Yaofeng Yuan, Kuo-Wei Huang, Mild copper-catalyzed trifluoromethylation of terminal alkynes using an electrophilic trifluoromethylating reagent Tetrahedron. ,vol. 68, pp. 2527- 2531 ,(2012) , 10.1016/J.TET.2011.12.085
Rong Zhu, Stephen L. Buchwald, Copper-Catalyzed Oxytrifluoromethylation of Unactivated Alkenes Journal of the American Chemical Society. ,vol. 134, pp. 12462- 12465 ,(2012) , 10.1021/JA305840G
Deng-Fu Lu, Cheng-Liang Zhu, Hao Xu, Copper(I)-catalyzed diastereoselective hydroxytrifluoromethylation of dienes accelerated by phosphine ligands Chemical Science. ,vol. 4, pp. 2478- 2482 ,(2013) , 10.1039/C3SC50582K