31P and 195 Pt NMR studies on fluxional η1-ligated 1,2,4-triphosphacyclopentadienyl palladium(II) and platinum(II) complexes

作者: John F. Nixon , Gary J.D. Sillett

DOI: 10.1016/0022-328X(93)83298-A

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摘要: Abstract Detailed 31 P and 195 Pt NMR studies on complexes of the type trans -[MCl(P 3 C 2 t Bu )(PR ) ], -[M(P (PR (M  Pd, Pt), cis -[Pt(P (dppe)], including variable temperature measurements, have given information (i) structures complexes, (ii) mechanism ‘fluxional’ process involving ring, (iii) signs certain coupling constants.

参考文章(6)
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