Arsenic leachability in water treatment adsorbents.

作者: Chuanyong Jing , Suqin Liu , Manish Patel , Xiaoguang Meng

DOI: 10.1021/ES050290P

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摘要: Arsenic leachability in water treatment adsorbents was studied using batch leaching tests, surface complexation modeling and extended X-ray absorption fine structure (EXAFS) spectroscopy. Spent were collected from five pilot-scale filters that tested for removal of arsenic groundwater Southern New Jersey. The spent media included granular ferric hydroxide (GFH), oxide, titanium dioxide, activated alumina, modified alumina. As determined with the Toxicity Characteristic Leaching Procedure (TCLP, 0.1 M acetate solution) below 180 μg L-1 all media. leachate concentration California Waste Extraction Test (0.2 citrate more than 10 times higher TCLP reached as high 6650 GFH sample. EXAFS results indicate forms inner-sphere bidentate binuclear complexes on adsorbent surfaces. adsorption/desorption behaviors each media...

参考文章(26)
W. Driehaus, M. Jekel, U. Hildebrandt, Granular ferric hydroxide—a new adsorbent for the removal of arsenic from natural water. Journal of Water Supply Research and Technology-aqua. ,vol. 47, pp. 30- 35 ,(1998) , 10.2166/AQUA.1998.0005
Ross Nickson, John McArthur, William Burgess, Kazi Matin Ahmed, Peter Ravenscroft, Mizanur Rahmanñ, None, Arsenic poisoning of Bangladesh groundwater Nature. ,vol. 395, pp. 338- 338 ,(1998) , 10.1038/26387
George P. Korfiatis, Christos Christodoulatos, David J. Moll, Xiaoguang Meng, Mazakhir Dadachov, Robert E. Reim, Geofrey Paul Onifer, Daniel B. Rice, Chan Han, Fredrick W. Vance, Harlan Robert Goltz, William I. Harris, Methods of preparing a surface-activated titanium oxide product and of using same in water treatment processes ,(2005)
Matthew Newville, IFEFFIT: interactive XAFS analysis and FEFF fitting. Journal of Synchrotron Radiation. ,vol. 8, pp. 322- 324 ,(2001) , 10.1107/S0909049500016964
Sunbaek Bang, Manish Patel, Lee Lippincott, Xiaoguang Meng, Removal of arsenic from groundwater by granular titanium dioxide adsorbent Chemosphere. ,vol. 60, pp. 389- 397 ,(2005) , 10.1016/J.CHEMOSPHERE.2004.12.008
Xiaoguang Meng, George P. Korfiatis, Chuanyong Jing, Christos Christodoulatos, Redox transformations of arsenic and iron in water treatment sludge during aging and TCLP extraction. Environmental Science & Technology. ,vol. 35, pp. 3476- 3481 ,(2001) , 10.1021/ES010645E
G.A Waychunas, B.A Rea, C.C Fuller, J.A Davis, Surface chemistry of ferrihydrite: Part 1. EXAFS studies of the geometry of coprecipitated and adsorbed arsenate Geochimica et Cosmochimica Acta. ,vol. 57, pp. 2251- 2269 ,(1993) , 10.1016/0016-7037(93)90567-G
Scott Fendorf, Matthew J. Eick, Paul Grossl, Donald L. Sparks, Arsenate and Chromate Retention Mechanisms on Goethite. 1. Surface Structure Environmental Science & Technology. ,vol. 31, pp. 315- 320 ,(1997) , 10.1021/ES950653T
W.P. Miller, L.W. Zelazny, D.C. Martens, Dissolution of synthetic crystalline and noncrystalline iron oxides by organic acids Geoderma. ,vol. 37, pp. 1- 13 ,(1986) , 10.1016/0016-7061(86)90039-X
Han Yong, W. H. Van Riemsdijk, Interfacial Charging Phenomena of Aluminum (Hydr)oxides Langmuir. ,vol. 15, pp. 5942- 5955 ,(1999) , 10.1021/LA981301D