Top-down tailoring of nanostructured manganese molybdate enhances its lithium storage properties

作者: Lifeng Zhang , Kechao Shen , Yangguang Li , Tong Zha , Yifei Song

DOI: 10.1039/C9CE01023H

关键词:

摘要: Binary transition metal oxide manganese molybdate is progressively tailored by a facile top-down strategy using dopamine as scissors. Aggregated micron-whisker structures are successfully converted to nanospheres in the aqueous phase at room temperature, whose morphology evolution witnessed direct observation of scanning electron microscopy. Meanwhile, nitrogen-doped carbon introduced composite after and controllable annealing treatment. Benefiting from structure tailoring surface modification, formed molybdate/nitrogen-doped composites exhibit highly reversible capacity excellent long-term cycling stability when evaluated anodes for lithium ion batteries. It believed that this synchronously regulating properties will inspire variation structural design other molybdate/carbon composites.

参考文章(41)
Qing Xia, Hailei Zhao, Zhihong Du, Zhipeng Zeng, Chunhui Gao, Zijia Zhang, Xuefei Du, Andrzej Kulka, Konrad Świerczek, Facile synthesis of MoO3/carbon nanobelts as high-performance anode material for lithium ion batteries Electrochimica Acta. ,vol. 180, pp. 947- 956 ,(2015) , 10.1016/J.ELECTACTA.2015.09.042
Shaikshavali Petnikota, Sandeep K. Marka, Vadali V.S.S. Srikanth, Mogalahalli V. Reddy, Bobba V.R. Chowdari, Elucidation of few layered graphene-complex metal oxide (A2Mo3O8, A = Co, Mn and Zn) composites as robust anode materials in Li ion batteries Electrochimica Acta. ,vol. 178, pp. 699- 708 ,(2015) , 10.1016/J.ELECTACTA.2015.08.066
Yaping Chen, Borui Liu, Wei Jiang, Qi Liu, Jingyuan Liu, Jun Wang, Hongsen Zhang, Xiaoyan Jing, Coaxial three-dimensional CoMoO 4 nanowire arrays with conductive coating on carbon cloth for high-performance lithium ion battery anode Journal of Power Sources. ,vol. 300, pp. 132- 138 ,(2015) , 10.1016/J.JPOWSOUR.2015.09.011
Sung-Soo Kim, Seiichiro Ogura, Hiromasa Ikuta, Yoshiharu Uchimoto, Masataka Wakihara, Reaction mechanisms of MnMoO4 for high capacity anode material of Li secondary battery Solid State Ionics. ,vol. 146, pp. 249- 256 ,(2002) , 10.1016/S0167-2738(01)01013-X
Kang Xiao, Lu Xia, Guoxue Liu, Suqing Wang, Liang-Xin Ding, Haihui Wang, Honeycomb-like NiMoO4 ultrathin nanosheet arrays for high-performance electrochemical energy storage Journal of Materials Chemistry. ,vol. 3, pp. 6128- 6135 ,(2015) , 10.1039/C5TA00258C
Le Yu, Lei Zhang, Hao Bin Wu, Genqiang Zhang, Xiong Wen (David) Lou, Controlled synthesis of hierarchical CoxMn3−xO4 array micro-/nanostructures with tunable morphology and composition as integrated electrodes for lithium-ion batteries Energy and Environmental Science. ,vol. 6, pp. 2664- 2671 ,(2013) , 10.1039/C3EE41181H
Jinlong Liu, Dong Qian, Haibo Feng, Junhua Li, Jianbo Jiang, Sanjun Peng, Youcai Liu, Designed synthesis of TiO2-modified iron oxides on/among carbon nanotubes as a superior lithium-ion storage material Journal of Materials Chemistry. ,vol. 2, pp. 11372- 11381 ,(2014) , 10.1039/C4TA01596G
Yunjiu Cao, Wenyao Li, Kaibing Xu, Yuxin Zhang, Tao Ji, Rujia Zou, Jianmao Yang, Zongyi Qin, Junqing Hu, MnMoO4·4H2O nanoplates grown on a Ni foam substrate for excellent electrochemical properties Journal of Materials Chemistry. ,vol. 2, pp. 20723- 20728 ,(2014) , 10.1039/C4TA04019H
N.N Leyzerovich, K.G Bramnik, T Buhrmester, H Ehrenberg, H Fuess, Electrochemical intercalation of lithium in ternary metal molybdates MMoO4 (M: Cu, Zn, Ni and Fe) Journal of Power Sources. ,vol. 127, pp. 76- 84 ,(2004) , 10.1016/J.JPOWSOUR.2003.09.010
Wei Xiao, Jun Song Chen, Chang Ming Li, Rong Xu, Xiong Wen Lou, Synthesis, Characterization, and Lithium Storage Capability of AMoO4 (A = Ni, Co) Nanorods† Chemistry of Materials. ,vol. 22, pp. 746- 754 ,(2010) , 10.1021/CM9012014