PHOTOELECTRON SPECTRA OF METALLOFULLERENES, GDC82 AND LA2C80 : ELECTRON TRANSFER FROM THE METAL TO THE CAGE
作者： Shojun Hino , Kazunori Umishita , Kentaro Iwasaki , Takafumi Miyazaki , Takayuki Miyamae
DOI: 10.1016/S0009-2614(97)01215-3
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摘要: Abstract Ultraviolet photoelectron spectra of metallofullerenes, GdC 82 and La 2 C 80 were measured with synchrotron orbital radiation. The specimens dried-up films prepared from their solution instead the sublimed commonly adopted for measurement. gave structure rich reflecting its electronic structure. band intensity depends on incident photon energy, as observed in other fullerenes. similarity to those LaC indicates that structures are analogous. spectrum does not show any characteristic have been fullerenes, it resembles amorphous carbon. ls core these metallofullerenes obtained Mg Kα radiation also presented.
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