Physico-chemical data required for the design of near-critical fluid extraction process

作者: M. B. King , O. Catchpole

DOI: 10.1007/978-94-011-2138-5_7

关键词:

摘要: Before the chemical engineering design of a proposed process can be initiated, values (or good estimates) will required for number physico-chemical properties both pure components (these are usually comparatively easy to find) and relevant mixtures. Extraction processes involving near-critical solvents no more less demanding than other, conventional, in this respect. Figures 1.16, 1.17 1.18, example, also 9.2 9.3 show simplified layouts possible extracting beds solids or liquid streams with solvent. In these cases disengagement solute from solvent gas is achieved by throttling expansion. When carrying out simple type, phase equilibria mixtures material extractors solvent/solute separator. Mass transfer rate data sizing continuous Figure 1.18 9.2. They evaluating performance extractor units (V1, V2, V3 10.2 5 9.3) used batch extraction solids.

参考文章(97)
G. Schmidt, H. Wenzel, A modified van der Waals type equation of state Chemical Engineering Science. ,vol. 35, pp. 1503- 1512 ,(1980) , 10.1016/0009-2509(80)80044-3
David H. Ziger, Charles A. Eckert, Correlation and prediction of solid-supercritical fluid phase equilibriums Industrial & Engineering Chemistry Process Design and Development. ,vol. 22, pp. 582- 588 ,(1983) , 10.1021/I200023A005
Otto. Redlich, J. N. S. Kwong, On the Thermodynamics of Solutions. V. An Equation of State. Fugacities of Gaseous Solutions. Chemical Reviews. ,vol. 44, pp. 233- 244 ,(1949) , 10.1021/CR60137A013
Navin C. Patel, Amyn S. Teja, A NEW CUBIC EQUATION OF STATE FOR FLUIDS AND FLUID MIXTURES Chemical Engineering Science. ,vol. 37, pp. 463- 473 ,(1982) , 10.1016/0009-2509(82)80099-7
On the Dispersion of a Solute in a Fluid Flowing through a Tube Proceedings of The Royal Society A: Mathematical, Physical and Engineering Sciences. ,vol. 235, pp. 67- 77 ,(1956) , 10.1098/RSPA.1956.0065
K. R. Hall, L. C. Eagleton, Andreas Acrivos, Theodore Vermeulen, Pore- and Solid-Diffusion Kinetics in Fixed-Bed Adsorption under Constant-Pattern Conditions Industrial & Engineering Chemistry Fundamentals. ,vol. 5, pp. 212- 223 ,(1966) , 10.1021/I160018A011
Y. Adachi, B.C.-Y. Lu, H. Sugie, Three-parameter equations of state Fluid Phase Equilibria. ,vol. 13, pp. 133- 142 ,(1983) , 10.1016/0378-3812(83)80087-9
Chung-Sung Tan, Shuen-Kwei Liang, Din-Chung Liou, Fluid—solid mass transfer in a supercritical fluid extractor Chemical Engineering Journal. ,vol. 38, pp. 17- 22 ,(1988) , 10.1016/0300-9467(88)80049-2
Basil O. Brady, Chien Ping C. Kao, Kerry M. Dooley, F. Carl Knopf, Robert P. Gambrell, Supercritical extraction of toxic organics from soils Industrial & Engineering Chemistry Research. ,vol. 26, pp. 261- 268 ,(1987) , 10.1021/IE00062A014