A neutral Fe(III) compound exhibiting a two-step spin transition and dielectric anomalies
作者： Zhao-Yang Li , Jing-Wei Dai , Kevin J. Gagnon , Hong-Ling Cai , Takashi Yamamoto
DOI: 10.1039/C3DT51554K
关键词:
摘要: The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me)·H2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, Mossbauer spectroscopy, differential scanning calorimetry (DSC), magnetic susceptibility measurements. This photo-responsive shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating multifunctional properties of 1.
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