Synthesis of disubstituted amine-functionalized diene-based polymers
作者： Yue Yang , Valerie V. Sheares
DOI: 10.1016/J.POLYMER.2006.09.064
关键词:
摘要: Diene-based polymers with two amine groups within each repeat unit were successfully synthesized by bulk and solution free radical polymerization techniques. All polymers have exclusive 1, 4-microstructure. The number average molecular weights of the materials obtained were in the range of 30–52× 103g/mol using 2, 2′-azobisisobutyronitrile (AIBN), t-butyl peracetate (t-BPA), or t-butyl hydroperoxide (t-BHP) as the initiators. The highest molecular weight achieved was 72× 103g/mol when t-butyl peroxide (t-BPO) was used as …
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