Transfer of state multipoles in open shell molecule–open shell molecule scattering

作者: B. J. Whitaker , A. J. McCaffery

DOI: 10.1063/1.445163

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摘要: General expressions are derived for the transfer of state multipoles in open shell polyatomic–open polyatomic rotationally inelastic collisions. These then used to write circular polarizations spin and resolved spectral emission lines. Using distorted wave Born approximation (DWBA), polarization ratios calculated specific case H+NH2 The potential is decomposed into a spin‐dependent term an exchange using tensor methods facilitate calculation. Alternatively, scattering may be considered take place on singlet or triplet surfaces. An interesting feature results that reorientation appears faster surface than singlet.

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