LITHIUM-ION SIEVE PROPERTY OF λ;-TYPE MANGANESE OXIDE
作者： KENTA OOI , YOSHITAKA MIYAI , SHUNSAKU KATOH
DOI: 10.1080/07366298708918581
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摘要: ABSTRACT The adsorptive properties of A-Mn02for mono and divalent metal ions were investigated by pH titration measurements the distribution coefficients(Kd's) ions. curve showed an apparently monobasic acid type for a H+-Li+exchange. Those H+-K+and H+-Cs+exchanges nearly same as that blank titration. lithium ion uptake increased with increasing solution reached 5 meq/g at 11. X-ray diffraction analyses adsorption caused increase in lattice constant cubic unit cell. potassium cesium uptakes zero over range between 4 A-Mn02showed remarkably high Kd value ions, compared to cation exchange resin. selectivity sequences Na+< K+< Rb+< Cs+<< Li+for alkali Mg2+< Ca2+< Sr2+< Ba2+for alkaline earth Ni2+< Zn2+< Co2+< Cu2+for transition
sci-hub.se 参考文章(18)
Clearfield, Inorganic ion exchange materials CRC Press. ,(1982) , 10.1201/9781351073561
Robert E. Mesmer, Charles F. Baes, The hydrolysis of cations ,(1976)
Alan E. Rubin, John T. Wasson, Geochim. cosmochim. acta: Rubin A.E. and Wasson J. T. (1987) Chondrules, matrix and coarsegrained chondrule rims in the Allende meteorite: Origin, interrelationships and possible precursor components 51, 1923–1937 Geochimica et Cosmochimica Acta. ,vol. 52, pp. 2549- 2549 ,(1988) , 10.1016/0016-7037(88)90313-4
James W. Murray, The interaction of metal ions at the manganese dioxide-solution interface Geochimica et Cosmochimica Acta. ,vol. 39, pp. 505- 519 ,(1975) , 10.1016/0016-7037(75)90103-9
D. R. Rosseinsky, Electrode Potentials and Hydration Energies. Theories and Correlations Chemical Reviews. ,vol. 65, pp. 467- 490 ,(1965) , 10.1021/CR60236A004
MASAHICHI TSUJI, MITSUO ABE, SYNTHETIC INORGANIC ION-EXCHANGE MATERIALS XXXVI. SYNTHESIS OF CRYPTOMELANE-TYPE HYDROUS MANGANESE DIOXIDE AS AN ION-EXCHANGE MATERIAL AND THEIR ION-EXCHANGE SELECTIVITIES TOWARDS ALKALI AND ALKALINE EARTH METAL IONS Solvent Extraction and Ion Exchange. ,vol. 2, pp. 253- 274 ,(1984) , 10.1080/07366298408918447
D.G. Wickham, W.J. Croft, Crystallographic and magnetic properties of several spinels containing trivalent ja-1044 manganese Journal of Physics and Chemistry of Solids. ,vol. 7, pp. 351- 360 ,(1958) , 10.1016/0022-3697(58)90285-3
W.I.F. David, M.M. Thackeray, P.G. Bruce, J.B. Goodenough, Lithium insertion into βMnO2 and the rutile-spinel transformation Materials Research Bulletin. ,vol. 19, pp. 99- 106 ,(1984) , 10.1016/0025-5408(84)90015-1
A. Mosbah, A. Verbaere, M. Tournoux, Phases LixMnO2λ rattachees au type spinelle Materials Research Bulletin. ,vol. 18, pp. 1375- 1381 ,(1983) , 10.1016/0025-5408(83)90045-4
Akiya Kozawa, On an Ion-Exchange Property of Manganese Dioxide Journal of The Electrochemical Society. ,vol. 106, pp. 552- 556 ,(1959) , 10.1149/1.2427436