A new synthesis of α,β-unsaturated aldehydes
作者： Jean-Marc Nuzillard , Ahcene Boumendjel , Georges Massiot
DOI: 10.1016/S0040-4039(01)80653-5
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摘要: Abstract The two carbon homologation of carbonyl compounds to α,β-unsaturated aldehydes is achieved by the Wittig-Horner reaction with N-methoxy N-methyl diethylphosphonoacetamide 1 followed lithium aluminum hydride reduction.
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sci-hub.se 参考文章(4)
James H. Babler, Michael J. Coghlan, A Facile Method for the Bishomologation of Ketones to α,β-Unsaturated Aldehydes: Application to the Synthesis of the Cyclohexanoid Components of the Boll Weevil Sex Attractant Synthetic Communications. ,vol. 6, pp. 469- 474 ,(1976) , 10.1080/00397917608082626
Steven Nahm, Steven M. Weinreb, N-methoxy-n-methylamides as effective acylating agents Tetrahedron Letters. ,vol. 22, pp. 3815- 3818 ,(1981) , 10.1016/S0040-4039(01)91316-4
S. Trippett, D. M. Walker, 405. The use, in Wittig reactions, of phosphonium salts and phosphobetaines containing a basic group Journal of the Chemical Society (Resumed). pp. 2130- 2133 ,(1961) , 10.1039/JR9610002130
Jean-Alain Fehrentz, Bertrand Castro, An efficient synthesis of optically active α-(t-butoxycarbonylamino)-aldehydes from α-amino acids Synthesis. ,vol. 1983, pp. 676- 678 ,(1983) , 10.1055/S-1983-30471