Multichannel complex scaled Titchmarsh Weyl theory a model for diatomic fragmentation

作者: Erkki Brändas , Magnus Rittby , Nils Elander

DOI: 10.1007/3-540-50994-1_49

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摘要: A single channel Titchmarsh-Weyl resonance scattering theory is extended to a coupled equations formulation. It demonstrated that the intrinsic simplicity of persists also in multichannel case. Explicit theorems connection with case are proved, and simple Wronskian expressions for resonant wave functions related physical quantities derived. The computational features illustrated by an application non-trivial curve crossing problem. numerical results display detailed behaviour poles complex plane. relevant diabatic and/or adiabatic limits as well effect strength interaction on structures studied. Applications modeling laser photofragment spectroscopy data finally mentioned

参考文章(53)
B.R. Junker, Recent Computational Developments in the use of Complex Scaling in Resonance Phenomena Advances in atomic and molecular physics. ,vol. 18, pp. 207- 263 ,(1982) , 10.1016/S0065-2199(08)60242-0
H. Lefebvre-Brion, R. Colin, Anomalous isotope effects in indirect predissociations: An example in the spectrum of BeH Journal of Molecular Spectroscopy. ,vol. 65, pp. 33- 45 ,(1977) , 10.1016/0022-2852(77)90356-3
L. Streit, S. Albeverio, L. S. Ferreira, Resonances: Models and Phenomena ,(1985)
Magnus Rittby, Nils Elander, Erkki Brändas, Weyl's theory and the method of complex rotation Molecular Physics. ,vol. 45, pp. 553- 572 ,(1982) , 10.1080/00268978200100431
Erik Balslev, Resonances, resonance functions and spectral deformations Resonances -- Models and Phenomena. ,vol. 211, pp. 27- 63 ,(1984) , 10.1007/3-540-13880-3_65
Sungyul Lee, Carl J. Williams, Karl F. Freed, Non-adiabatic effects on oxygen atom fine structure populations in the predissociation of the A2Σ+ state of OH Chemical Physics Letters. ,vol. 130, pp. 271- 277 ,(1986) , 10.1016/0009-2614(86)80468-7
Michael Hehenberger, Harold V. McIntosh, Erkki Brändas, Weyl's theory applied to the Stark effect in the hydrogen atom Physical Review A. ,vol. 10, pp. 1494- 1506 ,(1974) , 10.1103/PHYSREVA.10.1494
L Klynning, H Martin, Ionic Bonds in the Group IIA Hydrides Physica Scripta. ,vol. 20, pp. 594- 598 ,(1979) , 10.1088/0031-8949/20/5-6/006
Russell T Pack, Joseph O. Hirschfelder, Energy Corrections to the Born–Oppenheimer Approximation. The Best Adiabatic Approximation The Journal of Chemical Physics. ,vol. 52, pp. 521- 534 ,(1970) , 10.1063/1.1673017