Experimental Identification of the Ground State of BN in a Rare‐Gas Matrix
作者： Oren A. Mosher , R. P. Frosch
DOI: 10.1063/1.1672859
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摘要: The free radical BN has been obtained in Ne and Ar matrices by photolyzing H3BNH3. was identified observing the A 3Π ← X 3Π transition which is analogous to C2 Swan bands. It found that ground state of an matrix 3Π. No significant vibrational perturbation observed. 0–0 band at 27 931 721 cm−1 Ar, respectively, compared with a gas‐phase value 776 cm−1. ΔG1/2 upper 1288 which, within experimental error, identical value.
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