Building Light‐Emitting Metal‐Organic Frameworks by Post‐Synthetic Modification
作者： Reda M. Abdelhameed , Duarte Ananias , Artur M. S. Silva , João Rocha
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摘要: Ln3+-bearing Metal-Organic Frameworks (MOFs) are attracting much attention because of their unique luminescence properties and the possibility fine-tuning metal coordination spheres by post-synthetic modification (PSM). Here, we report PSM well-known IRMOF-3 reaction with methyl 3-chloro-3-oxopropanoate pyridine-2,6-dicarbonyl dichloride affording, respectively, IRMOF-3-CM IRMOF-3-PY. 1H NMR digested modified samples showed ca. 100 % conversion amino group. The pendant groups were subsequently used to coordinate Eu+3 Tb3+ materials studied.
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