Electrophoretic study of RuO2/γ‐Al2O3 samples used in the water gas shift reaction

作者: S. A. Moya , A. Mansilla , F. J. Gil Llambías

DOI: 10.1002/BSCB.19880970102

关键词:

摘要: RuCl3 supported on γ-Al2O3 and calcined in air at 550°C generates an active catalytic phase for the water-gas-shift-reaction, 100–140°C atmospheric pressure. Both apparent surface coverage of alumina by RuCl3, as measured electrophoresis, activity occur simultaneously with metal deposited samples.

参考文章(12)
FJ Gil-Llambias, AM Escudey, JL García Fierro, A Lopez Agudo, Determination of the active surface area of vanadia by electrophoretic migration and XPS measurements Journal of Catalysis. ,vol. 95, pp. 520- 526 ,(1985) , 10.1016/0021-9517(85)90130-7
Francisco J. Gil-Llambías, A. M. Escudey-Castro, Use of zero point charge measurements in determining the apparent surface coverage of molybdena in MoO3/γ-Al2O3 catalysts Journal of The Chemical Society, Chemical Communications. pp. 478- 479 ,(1982) , 10.1039/C39820000478
A.M. Escudey-Castro, L. Broussieres McLeod, F.J. Gil-Llambías, Apparent surface coverage by molybdenum of oxidized, sulfided and reoxidized Mo/γ-Al2O3 catalysts Applied Catalysis. ,vol. 4, pp. 371- 376 ,(1982) , 10.1016/0166-9834(82)80134-6
M. Shelef, H. S. Gandhi, Ammonia Formation in the Catalytic Reduction of Nitric Oxide. III. The Role of Water Gas Shift, Reduction by Hydrocarbons, and Steam Reforming Industrial & Engineering Chemistry Product Research and Development. ,vol. 13, pp. 80- 85 ,(1974) , 10.1021/I360049A016
Richard L. Klimisch, Kathleen C. Taylor, Catalytic Reduction of Nitric Oxide on Ruthenium Industrial & Engineering Chemistry Product Research and Development. ,vol. 14, pp. 26- 29 ,(1975) , 10.1021/I360053A005
D KING, A Fischer-Tropsch study of supported ruthenium catalysts Journal of Catalysis. ,vol. 51, pp. 386- 397 ,(1978) , 10.1016/0021-9517(78)90277-4
J GOODWIN, Characterization of highly dispersed Ru catalysts by chemisorption Journal of Catalysis. ,vol. 68, pp. 227- 232 ,(1981) , 10.1016/0021-9517(81)90063-4
C. P. P. Singh, D. N. Saraf, Simulation of High-Temperature Water-Gas Shift Reactors Industrial & Engineering Chemistry Process Design and Development. ,vol. 16, pp. 313- 319 ,(1977) , 10.1021/I260063A012