Optical Study of α-Fe2O3 under Ultrahigh Pressure

作者: Tetsuya Kawamura , Shoichi Endo , Michihiro Kobayashi , Shin-ichiro Narita

DOI: 10.1143/JPSJ.53.3684

关键词:

摘要: An optical measurement was made for α-Fe 2 O 3 under ultrahigh pressure generated by a diamond cell. Low-energy shifts of the absorptions due to 6 A 1 g → 4 T and transitions in 3d electrons Fe ion were observed with increasing up 300 kbar. The increase crystal-field splitting indicated from data. new absorption at higher is supposed be ascribed high spin-low spin transition.

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