Studies on miscibility of dehydrated castor oil epoxy blend with poly(methyl methacrylate)

作者: S. M. Ashraf , Sharif Ahmad , Ufana Riaz , H. O. Sharma

DOI: 10.1002/APP.22138

关键词:

摘要: Oil epoxies can be used as plasticizers in the processing of hard polymers. For this purpose dehydrated castor oil epoxy (DCOE), a product from sustainable resource, has been chosen for blending with poly(methyl methacrylate) (PMMA) to investigate compatibility blend pair. Blends DCOE/PMMA were prepared weight ratios 80/20, 60/40, 40/60, and 20/80 through solution method by mixing dimethylsulphoxide. Free-standing films cast miscibility two components was investigated viscosity ultrasonic measurements, which provided valuable information on degree pairs blends solution. The also examined differential scanning calorimetry electron microscopy. All studies revealed that DCOE immiscible PMMA. However, appearance texture not found show any visible change over several months, indicates stability system. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3094–3100,

参考文章(27)
Siddaramaiah, P. Mallu, R. Somashekar, Characterization of castor oil–based interpenetrating polymer networks of PU/PS Journal of Applied Polymer Science. ,vol. 68, pp. 1739- 1743 ,(1998) , 10.1002/(SICI)1097-4628(19980613)68:11<1739::AID-APP3>3.0.CO;2-K
A.Varada Rajulu, P.Mabu Sab, Ultrasonic studies of water/poly(ethylene glycol) mixtures European Polymer Journal. ,vol. 32, pp. 267- 268 ,(1996) , 10.1016/0014-3057(95)00134-4
Xiao-Dong Fan, You-Lo Hsieh, John M. Krochta, Mark J. Kurth, Study on molecular interaction behavior, and thermal and mechanical properties of polyacrylic acid and lactose blends Journal of Applied Polymer Science. ,vol. 82, pp. 1921- 1927 ,(2001) , 10.1002/APP.2037
I. M. Thakore, Sonal Desai, B. D. Sarwade, Surekha Devi, Evaluation of compatibility of poly(vinyl chloride)/starch acetate blends using simple techniques Journal of Applied Polymer Science. ,vol. 71, pp. 1851- 1861 ,(1999) , 10.1002/(SICI)1097-4628(19990314)71:11<1851::AID-APP16>3.0.CO;2-W
Young Soo Soh, Miscibility of polymethyl methacrylate with poly(hydroxy ether) of bisphenol A Journal of Applied Polymer Science. ,vol. 45, pp. 1831- 1835 ,(1992) , 10.1002/APP.1992.070451017
A.K. Kulshreshtha, B.P. Singh, Y.N. Sharma, Viscometric determination of compatibility in PVC/ABS polyblends. I: Viscosity-composition plots European Polymer Journal. ,vol. 24, pp. 29- 31 ,(1988) , 10.1016/0014-3057(88)90121-8
Ashoka Ray, Micelle formation in pure ethylene glycol Journal of the American Chemical Society. ,vol. 91, pp. 6511- 6512 ,(1969) , 10.1021/JA01051A069
Junjie Chen, S. H. Goh, S. Y. Lee, K. S. Siow, Miscibility behavior of blends of poly(alkyl methacrylate)s with poly(p‐methylstyrene‐co‐methacrylonitrile) Journal of Applied Polymer Science. ,vol. 56, pp. 761- 767 ,(1995) , 10.1002/APP.1995.070560701