Palladium-Catalyzed Preparation of Dialkyl Allylphosphonates. A New Preparation of Diethyl 2-Oxoethylphosphonate

作者: R. Malet , M. Moreno-Mañas , R. Pleixats

DOI: 10.1080/00397919208019075

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摘要: Abstract Palladium-catalyzed Michaelis-Arbuzov reaction of allyl acetates with trialkyl phosphites affords dialkyl allylphosphonates. Diethyl 2-oxoethylphosphonate is efficiently prepared by ozonization diethyl allylphosphonate.

参考文章(20)
Rui Tamura, Masami Kato, Koji Saegusa, Masato Kakihana, Daihei Oda, Stereoselective E-olefin formation by Wittig-type olefination of aldehydes with allylic tributylphosphorus ylides derived from allylic nitro compounds Journal of Organic Chemistry. ,vol. 52, pp. 4121- 4124 ,(1987) , 10.1021/JO00227A034
Wesley G. Bentrude, Sueg Geun Lee, Kunihiko Akutagawa, Wei Zhen Ye, Yves Charbonnel, Photoinduced electrocyclic rearrangements of allyl phosphites via possible phosphoranyl 1,3-biradicals Journal of the American Chemical Society. ,vol. 109, pp. 1577- 1579 ,(1987) , 10.1021/JA00239A052
M. Moreno-Mañas, R. M. Ortuño, M. Prat, M. A. Galán, The One-Pot Palladium Catalyzed Wittig Reaction with Allylic Alcohols. Scope and Limitations Synthetic Communications. ,vol. 16, pp. 1003- 1013 ,(1986) , 10.1080/00397918608056342
Xiyan Lu, Jingyang Zhu, Jilin Huang, Xiaochun Tao, Allylic carbon-phosphorus bond formation catalyzed by nickel complexes Journal of Molecular Catalysis. ,vol. 41, pp. 235- 243 ,(1987) , 10.1016/0304-5102(87)80031-7
Toshikazu Hirao, Toshio Masunaga, Naoto Yamada, Yoshiki Ohshiro, Toshio Agawa, Palladium-catalyzed New Carbon-Phosphorus Bond Formation Bulletin of the Chemical Society of Japan. ,vol. 55, pp. 909- 913 ,(1982) , 10.1246/BCSJ.55.909
Gerhard Bauer, Eberhard Breitmaier, Carbon-13 NMR spectroscopy ,(1987)
Rui Tamura, Koji Saegusa, Masato Kakihana, Daihei Oda, Stereoselective E and Z olefin formation by Wittig olefination of aldehydes with allylic phosphorus ylides: stereochemistry Journal of Organic Chemistry. ,vol. 53, pp. 2723- 2728 ,(1988) , 10.1021/JO00247A012