Deuterium separation by ultraviolet laser dissociation of formaldehyde
作者： L. Mannik , S. K. Brown
DOI: 10.1063/1.330093
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摘要: Irradiation of natural isotopic abundance formaldehyde with a narrow linewidth ultraviolet laser has yielded high deuterium enrichments (>600 at 5 Torr, 303 K) five wavelengths in the range 340 to 355 nm. The temperature and pressure dependence have been measured for both enrichment selectivity, latter being determined from resolution spectra deuterated formaldehyde. In general, conditions investigated (293–343 K; 2–26 Torr), selectivity are decreasing functions pressure, but certain cases is independent over small range. highest (1110) was 2 293 K, 352.061 results can be explained terms hot bands as well Doppler broadening absorption bands. For all wavelengths, larger than low (<6 yet two equal higher pressure. This...
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